A History of Science — Volume 5Williams, Henry Smith
History
A History of Science — Volume 5
Williams, Henry Smith
Science -- History
If the vacuum vessel containing a liquefied gas be kept in a cold
medium, and particularly if two vacuum tubes be placed together, so that
no exposed surface of liquid remains, a portion of liquefied air, for
example, may be kept almost indefinitely. Thus it becomes possible
to utilize the liquefied gas for experimental investigation of the
properties of matter at low temperatures that otherwise would be quite
impracticable. Great numbers of such experiments have been performed in
the past decade or so by all the workers with low temperatures already
mentioned, and by various others, including, fittingly enough, the
holder of the Rumford professorship of experimental physics at Harvard,
Professor Trowbridge. The work of Professor Dewar has perhaps been the
most comprehensive and varied, but the researches of Pictet, Wroblewski,
and Olzewski have also been important, and it is not always possible
to apportion credit for the various discoveries accurately, since
the authorities themselves are in unfortunate disagreement in several
questions of priority. But in any event, such questions of exact
priority have no great interest for any one but the persons directly
involved. We may quite disregard them here, confining attention to the
results themselves, which are full of interest.
The questions investigated have to do with the physical properties,
such as electrical conductivity, magnetic condition, light-absorption,
cohesion, and chemical affinities of matter at excessively low
temperatures. It is found that in all these regards most substances are
profoundly modified when excessively cooled. Thus if a piece of any pure
metal is placed in an electric circuit and plunged into liquid air, its
resistance to the passage of the electricity steadily decreases as the
metal cools, until at the temperature of the liquid it is very trifling
indeed. The conclusion seems to be justified that if the metal could be
still further cooled until it reached the theoretical "absolute zero,"
or absolutely heatless condition, the electrical resistance would also
be nil. So it appears that the heat vibrations of the molecules of a
pure metal interfere with the electrical current. The thought suggests
itself that this may be because the ether waves set up by the vibrating
molecules conflict with the ether strain which is regarded by some
theorists as constituting the electrical "current." But this simple
explanation falters before further experiments which show, paradoxically
enough, that the electrical resistance of carbon exactly reverses what
has just been said of pure metals, becoming greater and greater as the
carbon is cooled. If an hypothesis were invented to cover this case
there would still remain a puzzle in the fact that alloys of metals
do not act at all like the pure metals themselves, the electrical
resistance of such alloys being, for the most part, unaffected by
changed temperature. On the whole, then, the facts of electrical
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