A History of Science — Volume 5Williams, Henry Smith
History
A History of Science — Volume 5
Williams, Henry Smith
Science -- History
If this increased strength and hardness of a contracted metal are
what one would expect on molecular principles, the decreased chemical
activity at low temperatures is no less natural-seeming, when one
reflects how generally chemical phenomena are facilitated by the
application of heat. In point of fact, it has been found that at the
temperature of liquid hydrogen practically all chemical activity
is abolished, the unruly fluorine making the only exception. The
explanation hinges on the fact that every atom, of any kind, has
power to unite with only a limited number of other atoms. When the
"affinities" of an atom are satisfied, no more atoms can enter into the
union unless some atoms already there be displaced. Such displacement
takes place constantly, under ordinary conditions of temperature,
because the vibrating atoms tend to throw themselves apart, and other
atoms may spring in to take the places just vacated--such interchange,
in fact, constituting the essence of chemical activity. But when the
temperature is reduced the heat-vibration becomes insufficient to
throw the atoms apart, hence any unions they chance to have made are
permanent, so long as the low temperature is maintained. Thus it is that
substances which attack one another eagerly at ordinary temperatures
will lie side by side, utterly inert, at the temperature of liquid air.
Under certain conditions, however, most interesting chemical experiments
have been made in which the liquefied gases, particularly oxygen, are
utilized. Thus Olzewski found that a bit of wood lighted and thrust into
liquid oxygen burns as it would in gaseous oxygen, and a red-hot iron
wire thrust into the liquid burns and spreads sparks of iron. But more
novel still was Dewar's experiment of inserting a small jet of ignited
hydrogen into the vessel of liquid oxygen; for the jet continued to
burn, forming water, of course, which was carried away as snow. The idea
of a gas-jet burning within a liquid, and having snow for smoke, is
not the least anomalous of the many strange conceptions that the
low-temperature work has made familiar.
PRACTICAL RESULTS AND ANTICIPATIONS
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