A History of Science — Volume 5Williams, Henry Smith
History
A History of Science — Volume 5
Williams, Henry Smith
Science -- History
There are at least two of the low-temperature phenomena, however,
that seem a little less puzzling--the facts, namely, that cohesion and
rigidity of structure are increased when a substance is cooled and that
chemical activity is very greatly reduced, in fact almost abolished.
This is quite what one would expect _a priori_--though no wise man would
dwell on his expectation in advance of the experiments--since the whole
question of liquids and solids _versus_ gases appears to be simply a
contest between cohesive forces that are tending to draw the molecules
together and the heat vibration which is tending to throw them apart.
As a substance changes from gas to liquid, and from liquid to solid,
contracting meantime, simply through the lessening of the heat
vibrations of its molecules, we might naturally expect that the solid
would become more and more tenacious in structure as its molecules came
closer and closer together, and at the same time became less and less
active, as happens when the solid is further cooled. And for once
experiment justifies the expectation. Professor De-war found that the
breaking stress of an iron wire is more than doubled when the wire
is cooled to the temperature of liquid air, and all other metals are
largely strengthened, though none other to quite the same degree.
He found that a spiral spring of fusible metal, which at ordinary
temperature was quickly drawn out into a straight wire by a weight
of one ounce, would, when cooled to -182 deg, support a weight of two
pounds, and would vibrate like a steel spring so long as it was cool.
A bell of fusible metal has a distinct metallic ring at this low
temperature; and balls of iron, tin, lead, or ivory cooled to -182
deg and dropped from a height, "in all cases have the rebound greatly
increased. The flattened surface of the lead is only one-third what it
would be at ordinary temperature." "These conditions are due solely to
the cooling, and persist only while the low temperature lasts."
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