A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
_Experiment No. II._--Lay a device cut from black paper upon a sheet
of sensitive paper, and compress the two together by means of a sheet
of glass. After a proper length of exposure the figure will be exactly
copied, the tint however being reversed: the black paper protecting the
sensitive Chloride beneath, produces a _white_ figure upon a dark ground.
_Experiment No. III._--Repeat the last experiment, substituting a piece
of lace or gauze-wire for the paper device. This is intended to show the
minuteness with which objects can be copied, since the smallest filament
will be distinctly represented.
_Experiment No. IV._--Take an engraving in which the contrast of light
and shade is tolerably well marked, and having laid it closely in contact
with the sensitive paper, expose as before. This experiment shows that the
surface darkens in degrees proportionate to the intensity of the light, so
that the _half_ shadows of the engraving are accurately maintained, and a
pleasing gradation of tone produced.
In the darkening of Photographic papers, the action of the light is quite
superficial, and although the black colour may be intense, yet the amount
of reduced Silver which forms it is so small that it cannot conveniently
be estimated by chemical reagents. This is well shown by the results of
an analysis performed by the Author, in which the total weight of Silver
obtained from a blackened sheet measuring nearly 24 by 18 inches amounted
to less than _half a grain_. It becomes therefore of great importance in
preparing sensitive paper to attend to the condition of the surface layer
of particles, the action rarely extending to those beneath. The use of
Albumen, Gelatine, etc., which will be explained in the eighth Chapter,
has reference to this amongst other advantages, and secures a better and
more sharply defined print.
CHAPTER III.
ON THE DEVELOPMENT OF AN INVISIBLE IMAGE BY MEANS OF A REDUCING AGENT.
It has been shown in the previous Chapter that the majority of the Salts
of Silver, both organic and inorganic, are darkened in colour on exposure
to light, and, by the loss of Oxygen, Chlorine, etc., become reduced to
the condition of _Sub_salts.
Many of the same compounds are also susceptible of a change under the
influence of light, which is even more remarkable. This change takes
place after a comparatively short exposure, and as it does not affect the
appearance of the sensitive layer, for some time it escaped notice: but
it was afterwards discovered that an impression, before invisible, might
be brought out by treating the plate with certain chemical agents which
are without effect on the original unchanged salt, but quickly blacken it
after exposure.
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