A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
It is a remarkable fact that the Silver compounds most readily affected by
light alone, are not the most sensitive to the reception of the invisible
image. Thus, of Photographic papers prepared with Chloride, Bromide, or
Iodide of Silver, the former assume the deepest shade of colour under the
influence of the sun's rays, but if all be exposed _momentarily_, and
then removed, the greatest amount of effect will be developed upon the
Iodide paper. Iodide of Silver therefore is the salt commonly used when
sensibility is an object, but it should be noted that images nearly or
quite latent can be impressed upon many other of the compounds of Silver,
including those belonging to the animal and vegetable kingdoms.
_Experiments illustrating the Formation of an Invisible Image._--Take a
sheet of sensitive paper, prepared with Iodide of Silver by the method
given in the fourth Chapter of Part II., and having divided it into two
parts, expose one of them to the luminous rays for a few seconds. No
visible decomposition takes place, but on removing the pieces to a room
dimly illuminated, and brushing with a solution of _Gallic Acid_, a
manifest difference will be observed; the one being unaffected, whilst the
other darkens gradually until it becomes black.
_Experiment II._--A prepared sheet is shielded in certain parts by an
opaque substance, and then after the requisite exposure, which is easily
ascertained by a few trials, treated with the Gallic Acid as before; in
this case the protected part remains white, whilst the other darkens to a
greater or less extent.
In the same way, copies of leaves, engravings, etc. may be made, very
correct in the shading and much resembling those produced by the prolonged
action of light alone upon the Chloride of Silver.
The object of employing a substance like Gallic Acid to _develope_ or
bring out to view an invisible image, in preference to forming the picture
by the direct action of light, unassisted by a developer, is the _economy
of time_ thereby effected. This is well shown in the results of some
experiments conducted by M. Claudet in the Daguerreotype process: he found
that with a sensitive layer of Bromo-Iodide of Silver, an intensity of
light three thousand times greater was required if the use of a developer
was omitted, and the exposure continued until the picture became visible
upon the plate.
To increase the sensitiveness of Photographic preparations is a point
of great consequence; and indeed, when the Camera is used, from the low
intensity of the luminous image formed in that instrument, no other plan
than the one above described would be practicable. Hence the advancement,
and indeed the very origin, of the Photographic Art, may be dated from the
first discovery of a process for bringing out to view an invisible image
by means of a reducing agent.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account