A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
The salt sold in commerce as Sel d'or is a double Hyposulphite of Gold and
Soda, containing one atom of the former salt to three of the latter, with
four atoms of water of crystallization. It is formed by adding one part of
Chloride of Gold, in solution, to three parts of Hyposulphite of Soda, and
precipitating the resulting salt by Alcohol: the Chloride of Gold must be
added to the Hyposulphite of Soda, and not the Soda salt to the Gold (see
page 250).
Properties.--Hyposulphite of Gold is unstable and cannot exist in an
isolated state, quickly passing into Sulphur, Sulphuric Acid, and metallic
Gold. When combined with excess of Hyposulphite of Soda in the form of Sel
d'or, it is more permanent.
Sel d'or occurs crystallized in fine needles, which are very soluble in
water. The commercial article is often impure, containing little else than
Hyposulphite of Soda, with a trace of Gold. It may be analyzed by adding
a few drops of strong Nitric Acid (free from Chlorine), diluting with
water, and afterwards collecting and igniting the yellow powder, which is
metallic Gold.
GRAPE SUGAR.
Symbol, C{24}H{28}O{28}. Atomic weight, 396.
This modification of Sugar, often termed _Granular Sugar_, or _Glucose_,
exists abundantly in the juice of grapes and in many other varieties of
fruit. It forms the saccharine concretion found in honey, raisins, dried
figs, etc. It may be produced artificially by the action of fermenting
principles and of dilute mineral acids, upon Starch.
_Properties._--Grape Sugar crystallizes slowly and with difficulty from
a concentrated aqueous solution, in small hemispherical nodules, which
are hard, and feel gritty between the teeth. It is much less sweet to the
taste than Cane Sugar, and not so soluble in water (1 part dissolves in
1-1/2 of cold water).
Grape Sugar tends to absorb Oxygen, and hence it possesses the property of
decomposing the salts of the noble metals, and reducing them by degrees
to the metallic state, even without the aid of light. _Cane_ Sugar does
not possess these properties to an equal extent, and hence it is readily
distinguished from the other variety. The product of the action of Grape
Sugar upon Nitrate of Silver appears to be a very low form of Oxide of
Silver combined with organic matter.
HONEY.
This substance contains two distinct kinds of Sugar, Grape Sugar, and an
uncrystallizable substance analogous to, or identical with, the Treacle
found associated with common Sugar in the cane-juice. The agreeable
taste of Honey probably depends upon the latter, but its reducing power
on metallic oxides is due to the former. Pure Grape Sugar can readily
be obtained from inspissated Honey, by treating it with Alcohol, which
dissolves out the syrup, but leaves the crystalline portion.
Much of the commercial article is adulterated, and, for Photographic use,
the Virgin Honey should be obtained direct from the comb.
HYDROCHLORIC ACID.
Symbol, HCl. Atomic weight, 37.
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