A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
The addition of _Nitric Acid_ to Sulphate of Iron modifies the
development, making it more slow and gradual, and producing a bright
sparkling surface of reduced Silver. Too much of this acid however must
not be used, or the action will be irregular. The Nitrate Bath also must
be tolerably concentrated, in order to compensate for the retarding effect
of Nitric Acid upon the development. The blue and transparent films of
Iodide of Silver, formed in a very dilute Nitrate Bath, are not well
adapted for Positives to be developed in this way. They are injured by the
acid, and the development of the image becomes imperfect.
_Protonitrate of Iron._--This salt, first used by Dr. Diamond, is
remarkable as giving a surface of brilliant metallic lustre without any
addition of free acid. Theoretically, it may be considered as closely
corresponding to the Sulphate of Iron with Nitric Acid added. There are
however slight practical differences between them, which are perhaps in
favour of the Protonitrate.
The reducing powers of _Protoxide_ of Iron appear to be in inverse ratio
to the strength of the acid with which it is associated in its salts;
hence the _Nitrate_ is by far the most feeble developer of the Protosalts
of Iron.
The rules already given for the use of Sulphate of Iron acidified with
Nitric Acid, apply also to the Nitrate of Iron; the proportion of free
Nitrate of Silver must be large, and the film of Iodide of Silver not too
transparent.
In developing direct Positives either by Pyrogallic Acid or the Salts of
Iron, the colour of the image will be found liable to some variation;
the character of the light, whether bright or feeble, and the length of
exposure in the Camera, affecting the result.
_A Process for whitening the Positive Image by means of Bichloride of
Mercury._--In place of brightening the Positive image by modifying the
developer, it was proposed some time since by Mr. Archer to effect the
same object by the use of the salt known as _Corrosive Sublimate_, or
Bichloride of Mercury.
The image is first developed in the usual way, fixed, and washed. It is
then treated with the solution of Bichloride, the effect of which is to
produce almost immediately an interesting series of changes in colour. The
surface first _darkens considerably_, until it becomes of an ash-grey,
approaching to black; shortly it begins to get lighter, and assumes a
_pure white_ tint, or a white slightly inclining to blue. It is then
seen, on examination, that the whole substance of the deposit is entirely
converted into this white powder.
The _rationale_ of the reaction of Bichloride of Mercury appears to be,
that the Chlorine of the mercurial salt divides itself between the Mercury
and the Silver, a portion of it passing to the latter metal and converting
it into a Protochloride. The white powder is therefore probably a compound
salt, as is further evidenced by the effects produced on treating it with
various reagents.
SECTION II.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account