A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
_On Collodion Negatives._
As in the case of a direct Positive we require an image which is _feeble_
though distinct, so, on the other hand, for a negative, it is necessary to
obtain one of considerable intensity. In the Chapter immediately following
the present, it will be shown that in using glass Negatives to produce
Positive copies upon Chloride of Silver paper, a good result cannot
be secured unless the Negative is sufficiently dark to obstruct light
strongly.
_The Collodion and Nitrate Bath for Negatives._--A Collodion containing
a very small portion of Iodide and yielding a blue transparent film in
the Bath is not well adapted for taking Negatives. Pale opalescent films
often give too little intensity in the high lights, and, unless the
Nitrate Bath be acid, do not admit of being exposed in the Camera for
the proper length of time without cloudiness and indistinctness of image
being produced under the action of the developer. The effect known as
"solarization of negatives," _i. e._ a red and translucent appearance
of the highest lights, is also more liable to occur when operating with
a very pale film. On the other hand, if the layer of Iodide be too
yellow and creamy, the half-tones of the image will often be imperfectly
developed, so that a middle point between these extremes is the best.
A pure and newly prepared Collodion, although highly sensitive to
light, does not always give, with one application of the developer, a
sufficiently vigorous image to serve as a negative matrix; and this
particularly in the most brightly illuminated parts, such as the sky in a
landscape photograph, or the white borders of an engraving. But on keeping
the Collodion for some weeks or months it becomes yellow, if iodized with
the alkaline iodides, and a decomposition takes place in it, as before
shown (p. 97), which lessens the rapidity of action, but adds to the
intensity of the negative.
Grape Sugar may be employed for the purpose of giving intensity to newly
mixed Collodion: also Glycyrrhizine, which is a resinous body extracted
from the root of Liquorice; but as both substances have an effect in
lessening the sensitiveness and keeping qualities of the fluid, they
should be used cautiously. In taking portraits in the open air, on bright
days, and with a Bath which has been mixed for a considerable time, it
will rarely be found that the intensity will be deficient; and especially
so if the developer be applied a second time to the film with a few drops
of solution of Nitrate of Silver added. In landscape Photography however,
or in copying engravings, where extreme sensitiveness is not an object,
the Glycyrrhizine may sometimes be added with advantage in order to obtain
perfect opacity of the blacks.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account