Heat performs work in two ways. First, it expands bodies—that is, it
draws their molecules farther apart against the force of cohesion which
binds them together or keeps them moving in definite orbits at definite
distances. It is as if it increased the velocity, and therefore the
centrifugal force of a system of planets, and so caused them to revolve
in wider orbits. The expansion of mercury in a thermometer affords a
familiar instance of this effect of heat and the readiest measure of its
amount. Secondly, it increases the energy of the molecular motions, so
that they dart about, collide, and vibrate with greater force. Thus, as
heat increases, evaporation increases, for molecules on the surface are
projected with so much force as to get beyond the sphere of the cohesive
attraction which binds them to the system, and they dart off like comets
into space. Finally, as heat increases, and more and more work is done,
against the centripetal force of cohesion, most substances, and doubtless
all if we could get heat enough, are converted from solids into fluids,
and ultimately into gases, in which latter state the molecules have got
altogether beyond the sphere of their mutual attraction, and tend to
dart off indefinitely in the direction of their own proper centrifugal
motions, unless confined, in which case they dart about, collide,
rebound, and exercise pressure on the containing surface.
Conversely, if heat expands bodies, it is given out when they contract.
Thus the enormous quantity of heat poured out for millions of years by
the sun, is probably owing mainly to the mechanical force of contraction
of the original cosmic matter condensing about the solar nucleus.
Again, when gases suddenly expand, their temperature falls, which is
the principle by which artificial ice is procured, and frozen beef and
mutton are brought from America and Australia, producing, such are the
complicated relations of modern society, agricultural depression, fall of
rents, and a serious aggravation of the Irish question.
Public-domain text, read in full here on John Shaqi.
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