As an example of the converse proposition of the transformation of heat
into mechanical work, the steam-engine affords the aptest illustration.
The original power came from the sun millions of years ago, and did work
by enabling the leaves of plants to overcome the strong mutual affinity
of carbon and oxygen in the carbonic dioxide in the air, and store up the
carbon in the plant, where it remained since the coal era in the form of
energy of position. By lighting the coal, or in other words separating
its molecules more widely by heat, we enable them to exert once more
their natural affinity for oxygen, and burn, that is recombine into
carbonic dioxide. The heat thus produced turns water into steam, which
passes through a cylinder, either into a condenser if the steam is at low
pressure, or into the outer air if it has been superheated and brought
to a higher pressure than that of the atmosphere. The difference of the
pressure or elasticity of the steam in the boiler, and of the same steam
when it is condensed or liberated, is available for doing work, and,
being admitted and released alternately at the two ends of the cylinder,
drives a piston up and down, which, by means of cranks and shafts,
turns a wheel or does whatever work is required of it. In doing this,
heat disappears, being converted into work, and the amount of heat would
exactly equal that into which the work would be converted according to
Joule’s law, if it could all be utilised without the loss necessarily
incurred by friction, radiation, and the still more important absorption
of latent heat required to convert water at boiling-point into vapour
of the same temperature. This latter is not really an annihilation of
the heat, but its conversion into work done in separating the molecules
against the force of cohesion. The whole heat, therefore, is transformed
into work, mainly molecular work in tearing molecules asunder, and the
residue into mechanical work turning spindles and driving locomotives and
steamboats.
Public-domain text, read in full here on John Shaqi.
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