A new system of chemical philosophy, Volume 2, Part 1 — John Shaqi
A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
from the 9 grains of gold; this would give 100 gold to 12.2 oxygen,
which is still nearer to the determination of Berzelius. Upon the whole
I am inclined to adopt the proportion of 8 to 1 or 100 to 12.5 as that
which appears the most correct approximation and at the same time a
ratio easily remembered and adapted to facilitate calculations.
We are now to consider whether the above is the protoxide. As no other
oxide has been clearly shewn to exist, and as this combines with
muriatic acid, with ammonia, with the oxide of tin, &c. and is wholly
deoxidated by green sulphate of iron and by a moderate heat, there
seems every reason to conclude it is a combination of the most simple
kind, or 1 atom of metal to 1 of oxygen. Hence the atom of oxygen being
7, that of gold must be 56, and not 140 or 200, as stated VOL. 1, p.
250.
Berzelius seems to consider the above as the tritoxide, or three atoms
of oxygen to one of gold; but it is extremely improbable that gold,
which is allowed to have a weak affinity for oxygen, should be able to
restrain the violent repulsion of three atoms of oxygen, and should on
every occasion lose them all at once, and not by degrees, as is usual
with other high oxides.
Subjoined are the results of various authors in regard to the oxide of
gold, but generally given with diffidence as to their accuracy.
gold oxygen
Bergman 100 + 10
Proust -- + 8.57 to 31.
Oberkampf -- + 10
Berzelius -- + 12 (4 suboxide)
My results -- + 12.5
Since writing the above I have had an opportunity of repeating the
experiments on the oxide of gold by an improved nitrous gas apparatus,
calculated almost entirely to exclude atmospheric air; I find less
nitrous gas produced during the solution than stated above, sometimes
by ⅓, and that it is variable according to the excess of nitric acid;
also that the solution requires a portion of oxymuriatic acid as an
equivalent for the nitrous gas retained. I prefer, however, the method
of oxidizing the green sulphate of iron; by putting a small excess of
the green sulphate and precipitating, first the red oxide and then the
green, I obtained very distinct results. On the whole I am inclined to
think my results preceding these have rather overrated the oxygen, and
that it would as nearly be stated at 11 on the hundred. This would be
nearly a mean of those in the above table, and would require the atom
of gold to be 63, and that of the oxide 70. Between the two extremes of
56 and 63 it is most probable the true weight of the atom of gold will
be found.
It may be proper to add that I have found 100 grain measures of
muriatic acid (1.16), and 25 of nitric (1.35), are sufficient to
dissolve 40 grains of standard gold; and I have reason to think the
acids are in due proportion nearly, though different from what is
usually recommended and employed.
2. _Oxide of Platina._
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