A new system of chemical philosophy, Volume 2, Part 1 — John Shaqi
A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
Platina exhibits greater difficulties than gold in the investigation
of its compounds with oxygen. It is not oxidized by heat; but by the
explosion of an electric battery it is converted into a black powder,
which is most probably the metal in extreme division, though it has
been considered by some as the protoxide. Platina is capable of being
oxidized and dissolved by nitro-muriatic acid, but less easily than
gold; it requires more acid, as high or higher temperature and long
continued digestion; nitrous gas is given out, during the solution,
but sparingly. When lime or an alkali is added to the solution with
a view to precipitate the oxide, a triple compound is usually formed
of the acid, the oxide and the alkali, which is in most instances
precipitated. This weighty compound renders the valuation of the oxygen
in it very uncertain.
Chenevix has made some observations on the oxides of platina, (see
Nichols. Journ. 7. p. 178.) He finds two oxides: the one consists of
93 platina and 7 oxygen; the other of 87 platina and 13 oxygen; but
the experiments on which these results rest are not quite satisfactory.
Mr. E. Davy in the 40th vol. of the Philos. Magazine, states his having
reduced the oxide of platina in solution by means of hydrogen; and
that he finds the oxide to consist of 84 platina and 16 oxygen nearly.
I could not succeed at all in effecting the reduction of the metal in
this way.
Berzelius has lately given us the results of his investigation on this
subject. (An. de Chimie 87--126.) According to this distinguished
chemist there are two oxides of platina; the first consists of 100
metal and 8¼ oxygen, and the second of 100 metal and 16½ oxygen,
nearly. In order to understand his process it may be proper to premise
that when nitro-muriatic acid has dissolved as much platina as it can,
there is still a great excess of one or both of the acids, which is
unnecessary for the existence of the solution, and which may, and in
general ought to be expelled by evaporation; by exposing the solution
to a heat of 100 or 150° the excess of both acids is in great part
driven off and a dry red mass is obtained, without smell, but very
deliquescent. It is equal to or rather more than twice the weight of
the platina. It consists of water, muriatic and nitric acids, oxygen
and platina; it is still an acid salt. By exposing the dry mass again
to a heat of 400 or 500°, it liquifies, exhales acid fumes having
the odour of oxymuriatic acid, and becomes again a dry mass of an
olive colour, exhaling fumes as the heat increases, and loses about
¼ of its weight. It is still soluble in water, except a few atoms of
black powder, continues acid to the tests, and may be considered as a
supermuriate of platina. If this olive powder be again heated almost to
red, it exhales a visible smoke in the open air, which has the smell
of oxymuriatic acid, and becomes a light brown powder, having lost a
little weight. It is then neither deliquescent nor soluble in water
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