A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
When an alloy is made, it seldom happens that the metal is perfect
and compact the first fusion; it is more or less porous, especially
when the two metals fuse at very different temperatures. By a second
fusion, which usually takes place at a much lower temperature than that
requisite for the first, the metal becomes compact and free from pores.
This is particularly the case with speculum metal; and I have little
doubt it is so with regard to many other alloys.
_Alloys of Gold with other Metals._
Gold unites with many of the metals by heat, and forms various alloys,
on which it may be proper to make a few remarks.
1. _Gold with platina._ Platina in a small proportion changes the
colour of gold towards white. 1 part to 20 gold makes it much paler.
1 to 11 gives it the colour of tarnished silver. 1 part with 4 of
gold has much the appearance of platina. The colour of gold does not
predominate till it becomes ⁸/₉ of the alloy. The alloy of 1 platina
and 11 gold is very ductile, and elastic when hammered. _Lewis.
Klaproth. Vauquelin._
2. _Gold with silver._ These two metals may be combined in almost any
proportion by fusion and proper treatment. Homberg found that when
equal parts of gold and silver are kept in fusion for a quarter of an
hour and then cooled, there were two masses, the uppermost pure silver,
the undermost an alloy of 5 parts gold and 1 silver. 1 part silver to
20 gold produces a sensible whiteness in the alloy. 2 parts gold and 1
of silver are stated to form the alloy of greatest hardness; this will
consist of 3 atoms of gold to 1 of silver.
3. _Gold with mercury._ See amalgams.
4. _Gold with copper._ Gold and copper form an alloy by fusion
together. 11 parts gold and 1 copper form the alloy used for gold coin.
The copper heightens the colour of the gold, and makes it harder and
less liable to wear. The current gold coin, however, usually contains
both silver and copper, but the weight of both does not much exceed
one twelfth of the whole. According to Muschenbroeck the maximum of
hardness is when 7 parts of gold and 1 part of copper are united. This
corresponds nearly to 6 atoms of gold and 1 of copper, the atom of gold
being estimated at 66 and that of copper at 56.
Other alloys of gold besides the above standard is that for watch
cases, which must contain at least ¾ pure gold. Watch chains, and
trinkets, are usually made of inferior alloy, called jewellers gold,
which is under no control. It rarely contains less than 30 per cent. of
pure gold.
5. _Gold with iron._ Gold and iron may be united by fusion in various
proportions. 11 parts gold and 1 iron form a ductile alloy which may
be rolled and stamped into coin. Its specific gravity is 16.885. The
colour is a pale yellowish gray approaching to white. The alloy is
harder than gold. When the iron is three or four times the weight
of gold, the alloy has the colour of silver. This last compound is
constituted of 1 atom of gold and 8 of iron nearly. _Lewis. Hatchett._
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