A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
In treating of Fluoric acid, (Vol. 1, page 277) we came to the
conclusion that this acid was probably constituted of two atoms of
oxygen, and one of hydrogen, and have figured it accordingly (Plate 5,
fig. 38). Subsequent experience however has shewn that deutoxide of
hydrogen, though it can be formed synthetically, is not the same thing
as fluoric acid. We are indebted to M. Thenard for the discovery of
this curious compound, the deutoxide of hydrogen or oxygenated water.
An ingenious memoir on the subject was published by him in 1818, in
which the formation and the properties of this compound are fully
detailed. I had no small satisfaction in 1822, when at Paris, in being
obligingly favoured by M. Thenard with a view of the process of the
formation, and of the more distinguishing properties of this singular
liquid.
The nature of fluoric acid is still enveloped in obscurity. My
experience led me to adopt the composition of fluate of lime to be 40
acid and 60 lime per cent. I had not then seen Scheele’s admirable
essay on the subject. From the 5th section of his 2d. essay on fluor
mineral, 1771, it may be deduced that fluate of lime is composed of
72.5 lime and 27.5 acid per cent. In 1809 Klaproth, and near the same
time, Dr. Thomson found about 67½ lime and 32½ acid per cent. in
fluor spar. They both erred, no doubt, as I did, by not repeating the
treatment of the mineral with sulphuric acid often enough. Since then
most authors, as Davy, Berzelius, Thomson, &c., agree with Scheele
nearly, in assigning 27.5 acid, and 72.5 lime, in 100 parts of fluate
of lime. My experience in 1820 gave me 1 per cent. less of lime; and
Dr. Thomson now finds about 1 per cent. more of lime than Scheele’s
analysis gives.
If we estimate the atom of lime at 24, that of fluoric acid must be
about 9, according with the above proportion; this is much below 15,
the weight of an atom of deutoxide of hydrogen.
Should Sir H. Davy’s view of fluate of lime be found correct, its
atomic constitution would be one atom of _calcium_, the metallic
substance of which lime is the protoxide, and one atom of _fluorine_,
the name he has assigned to the other element, which with hydrogen is
supposed to constitute the fluoric acid. The atom of fluor spar would
then be 1 atom of calcium, 17, united to one atom of fluorine 16.
MURIATIC ACID.--OXYMURIATIC ACID, &c.
From the articles _muriatic acid_ and _oxymuriatic acid_ in the former
volume, published now 16 years ago, as well as from the appendix
to said volume, in which sundry animadversions are found on the
fluctuating opinions entertained in regard to these acids, the reader
will not be surprised to find some further addition.
Public-domain text, read in full here on John Shaqi.
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