A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
Dr. Henry’s analysis of ammonia, in 1809, has been adverted to in our
article on the subject, vol. 1, page 429. The results of that Essay are
given in a tabular form; and the mean of six experiments was nearly
as we have stated, namely, that ammonia consists of 27¼ measures of
azote, and 72¾ hydrogen. To this it may be proper to add, that the two
extremes were, 26.1 azote and 73.9 hydrogen, and 28.2 azote with 71.8
hydrogen; also that a small error has crept into the table, which being
corrected, the average results are reduced to 27 and 73, very nearly.
Subsequently, both Dr. Henry and Sir H. Davy concurred in assigning 26
and 74 for the most approximating numbers. (See Nicholson’s Journal,
25, page 153). The true quantity of gases procured by the decomposition
of ammoniacal gas by electricity, was concluded by both these
authorities, to be 180 for each 100 of ammonia, when the requisite
precautions were taken, as we have related in vol. 1.
From what is stated above, it is evident the subject is one which
requires extraordinary skill and attention. This I can attest from my
own experience, which has been frequently renewed and varied; but the
results have not been sufficiently accordant to yield me satisfaction.
About ten years ago, I made several experiments on the decomposition
of ammonia, which, though they are not convincing, deserve, perhaps,
to be recorded in their results.--Some more recent experiments are
incorporated with them.
_Decomposition of ammonia by nitrous oxide._--I made many experiments,
by exploding mixtures of nitrous oxide and ammoniacal gases over
mercury. The excess of gas was mostly on the side of ammonia, but the
proportions were varied in the different experiments, from 10 vol.
nitrous oxide to 11 ammonia or to 5, which are about the extremes
capable of being fired by the electric spark.
When 10 parts nitrous oxide and 5 of ammonia are exploded over mercury,
the residuary gas contains some free oxygen and some nitrous acid
derived from the decomposition of the excess of nitrous oxide used;
with 6 parts of ammonia there is rarely any free oxygen. When 10 parts
of nitrous oxide, and 7 of ammonia are fired, I never found any free
oxygen or hydrogen; but when the ammonia is at or near 8 parts, I
find from ¹/₂₀ to ⅒ of the hydrogen from the ammonia in the residuary
gases. The two gases appear to be completely decomposed; the oxygen of
the nitrous oxide, as far as it can, unites with the hydrogen of the
ammonia, without forming any portion of nitrous acid or of free oxygen,
and the residue contains the azote of both gases, and the unburnt
hydrogen from the ammonia, as Dr. Henry first observed. This continues
to be the case till the ammonia becomes 11 parts, when the hydrogen
amounts to about ⅓ of the whole quantity which the ammonia yields.
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