A Practical Handbook on the Distillation of Alcohol from Farm Products — John Shaqi
A Practical Handbook on the Distillation of Alcohol from Farm ProductsWright, F. B. (Frederic B.)
Science
A Practical Handbook on the Distillation of Alcohol from Farm Products
Wright, F. B. (Frederic B.)
Alcohol; Alcohol, Denatured
In about three hours' time, the commencement of the fermentation is
announced by small bubbles of gas which appear on the surface of the vat,
and collect around the edges. As these increase in number, the whole
contents are gradually thrown into a state of motion, resembling violent
ebullition, by the tumultuous disengagement of carbonic anhydride. The
liquor rises in temperature and becomes covered with froth. At this
point, the vat must be covered tightly, the excess of gas finding an exit
through holes in the lid; care must now be taken to prevent the
temperature from rising too high, and also to prevent the action from
becoming too energetic, thereby causing the contents of the vat to
overflow. In about twenty-four hours the action begins to subside, and
the temperature falls to that of the surrounding atmosphere. An hour or
two later, the process is complete; the bubbles disappear, and the
liquor, which now possesses the characteristic odor and taste of alcohol,
settles out perfectly clear. The whole operation, as here described,
usually occupies from forty-eight to seventy-two hours. The duration of
the process is influenced, of course, by many circumstances, chiefly by
bulk of the liquor, its richness in sugar, the quality of the ferment,
and the temperature.
=Acetous Fermentation.= This perplexing occurrence cannot be too
carefully guarded against. It results when the fermenting liquor is
exposed to the air. When this is the case, the liquor absorbs a portion
of the oxygen, which unites with the alcohol, thus converting it into
acetic acid as rapidly as it is formed. When acetous fermentation begins,
the liquor becomes turbid, and a long, stringy substance appears, which
after a time settles down to the bottom of the vat. It is then found that
all the alcohol has been decomposed, and that an equivalent quantity of
acetous acid remains instead. It has been discovered that the presence of
a ferment and a temperature of 68∞ to 95∞ F. are indispensable to acetous
fermentation, as well as contact with the atmosphere. Hence, in order to
prevent its occurrence, it is necessary not only to exclude the air, but
also to guard against too high a temperature and the use of too much
ferment. The latter invariably tends to excite acetous fermentation. It
should also be remarked that it is well to cleanse the vats and utensils
carefully with lime water before using, in order to neutralize any acid
which they may contain; for the least trace of acid in the vat has a
tendency to accelerate the conversion of alcohol into vinegar. A variety
of other circumstances are favorable to acetification, such as the use of
a stagnant or impure water, and the foul odors which arise from the vats;
stormy weather or thunder will also engender it.
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