A Practical Handbook on the Distillation of Alcohol from Farm ProductsWright, F. B. (Frederic B.)
Science
A Practical Handbook on the Distillation of Alcohol from Farm Products
Wright, F. B. (Frederic B.)
Alcohol; Alcohol, Denatured
=Lactic Fermentation.= Under the influence of lactic fermentation, sugar
and starch are converted into lactic acid. When it has once begun, it
develops rapidly, and soon decomposes a large quantity of glucose; but as
it can proceed only in a neutral liquor, the presence of the acid itself
speedily checks its own formation. Then, however, another ferment is
liable to act upon the lactic acid already formed, converting it into
_butyric acid_, which is easily recognized by its odor of rank butter.
Carbonic anhydride and hydrogen are evolved by this reaction. The latter
gas acts powerfully upon glucose, converting it into a species of gum
called _mannite_, so that lactic fermentation--in itself an intolerable
nuisance--becomes the source of a new and equally objectionable waste of
sugar. It can be avoided only by keeping the vats thoroughly clean; they
should be washed with water acidulated with five per cent of sulphuric
acid. An altered ferment, or the use of too small a quantity, will tend
to bring it about.
The best preventives are _thorough cleanliness_, and the use of good,
fresh yeast in the correct proportion.
=Viscous Fermentation.= This is usually the result of allowing the vats
to stand too long before fermentation begins. It is characterized by the
formation of viscous or mucilaginous matters, which render the liquor
turbid, and by the evolution of carbonic anhydride and hydrogen gases the
latter acting as in the case of lactic fermentation and converting the
glucose into mannite. Viscous fermentation may generally be attributed to
the too feeble action of the ferment. It occurs principally in the
fermentation of white wines, beer, and beet-juice, or of other liquors
containing much nitrogenous matter. It may be avoided by the same
precautions as are indicated for the prevention of lactic fermentation.
=Periods of Fermentation.= The operation of fermentation may be
conveniently divided into three equal periods.
The first or pre-fermentation period is that when the yeast mixed into
the mash is growing; the temperature should then be kept at about 63 to
68∞ F. during which time the yeast is propagated. The growth of the yeast
is manifested by the development of carbonic acid gas and by a slight
motion of the mash. When alcohol is produced to an extent of say five per
cent. the growth of the yeast stops.
The second period of chief fermentation then begins. Carbonic acid is
freely developed and the sugar is converted into alcohol. The temperature
at this time should not exceed 81.5∞ F. The second period of fermentation
continues about 12 hours, when the last period commences.
During the third period or after fermentation there is a lessening of the
formation of carbonic acid and a lowering of the temperature. In this
stage the mash is kept at a temperature of 77∞ to 81∞ F.
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