A Practical Handbook on the Distillation of Alcohol from Farm ProductsWright, F. B. (Frederic B.)
Science
A Practical Handbook on the Distillation of Alcohol from Farm Products
Wright, F. B. (Frederic B.)
Alcohol; Alcohol, Denatured
A quick, if not always very exact, method consists in determining the
point at which the liquor boils. The boiling point of absolute alcohol
being once determined, it is obvious that the more it is diluted with
water the nearer will the boiling point of the mixture approach that of
water; moreover, it has been proved that the presence of saccharine and
other solid matters has but an almost inappreciable effect upon this
point. Field's alcoholometer, since improved by Ure, is based upon this
principle. It is shown in Fig. 53, and consists, roughly speaking, of a
cylindrical vessel _A_, to contain the spirit; this vessel is heated from
beneath by a spirit lamp, which fits into the case _B_. A delicate
thermometer _C_, the bulb of which is introduced into the spirit, is
attached to a scale divided into 100 divisions, of which each represents
one degree over-or under-proof. This method is liable to several small
sources of error, but when a great many determinations have to be made,
and speed is an object rather than extreme accuracy, this instrument
becomes exceedingly useful. It does not answer well with spirits _above_
proof, because the variation in their boiling points are so slight as not
to be easily observed with accuracy. But for liquors under-proof, and
especially for wines, beer, and other fermented liquors, it gives results
closely approximating to those obtained by distillation, and quite
accurate enough for all ordinary purposes. Strong liquors should
therefore be tested with twice their bulk, and commercial spirits with an
equal bulk, of water, the result obtained being multiplied by two or
three, as the case may be.
Another very expeditious, but somewhat rough, method was invented by
Geisler. It consists in measuring the tension of the vapor of the spirit,
by causing it to raise a column of mercury in a closed tube. The very
simple apparatus is shown in Fig. 54. _A_ is a small glass bulb, fitted
with a narrow tube and stop-cock. This vessel is completely filled with
the spirit, and is then screwed upon a long, narrow tube _B_, bent at one
end and containing mercury. This tube is attached to a graduated scale
showing the percentage of absolute alcohol above or below proof. To make
the test the cock is opened, and the bulb, together with the lower part
of the tube, is immersed in boiling water, which gradually raises the
spirit to its boiling-point. When this is reached, the vapor forces the
mercury up the tube, and, when stationary, the degree on the scale to
which it has ascended gives directly the percentage of alcohol.
[Illustration: FIG. 54.--Geisler's Apparatus.]
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