A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.Humphrey, S. D. (Samuel Dwight)
Science
A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.
Humphrey, S. D. (Samuel Dwight)
Ambrotype; Photography
"In using the mixed acids, the limits are the nitric acid being too
strong, in which case the product is insoluble, or too weak, when the
cotton becomes immediately matted or even dissolved, if the mixture
is warm. I have availed myself of these facts in order to produce
collodion-wool by the use of acids, without the trouble of calculating
the proper mixture according to their strength. Five parts by measure of
sulphuric acid, and four of nitric acid of specific gravity not lower
than 1·4, are mixed in an earthenware or thin glass vessel capable of
standing heat; small portions of water are added gradually (by half
drachms at a time, supposing two ounces to have been mixed,) testing after
each addition by immersion of a small portion of cotton; the addition of
water is continued until a fresh piece of cotton is found to contract and
dissolve on immersing; when this takes place, add half the quantity of
sulphuric acid previously used, and (if the temperature does not exceed
130°, in which case it must be allowed to cool to that point,) immerse
as much cotton, well pulled out, as can be easily and perfectly soaked;
it is to be left in for ten minutes, taking care that the mixture does
not become cold, and then transferred to cold water, and thoroughly
washed; this is a matter of much importance, and should be performed at
first by changing the water many times, until it ceases to taste acid,
and then treating it with boiling rain-water until the color of blue
litmus remains unchanged; the freedom from all trace of acid is insured
by adding a little ammonia before the last washing. Cotton thus prepared
should dissolve perfectly and instantaneously in ether containing a little
alcohol, without leaving a fibre behind, and the film it produces be of
the greatest strength and transparency, being what M. Gaudin terms 'rich
in gun-cotton.'
"The mixture of nitrate of potash and sulphuric acid is defective chiefly
from the want of fluidity, in consequence of which the cotton is less
perfectly acted on; this may be remedied by increasing the amount of
sulphuric acid, at the same time adding a little water; a mixture of 5
parts of dried nitre, with 10 of sulphuric acid, by weight, together
with 1 of water, produces a much better collodion wool than the ordinary
mixture of 1 of nitre with 1-1/2 of sulphuric acid. The nitre is _dried_
before weighing, in order that its amount, as well as that of the water
contained in the mixture, may be definite in quantity; it is then finely
powdered, mixed with the water, and the sulphuric acid added; the cotton
is immersed while the mixture is hot, and afterwards washed with greater
care even than is required when pure acids are used, on account of the
difficulty of getting rid of all the bisulphate of potash that adheres to
the fibres, which both acts as an acid and likewise causes the collodion
to appear opalescent when held up to the light; whereas the solution
should be perfectly transparent."
Plain Collodion.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account