A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper. — John Shaqi
A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.Humphrey, S. D. (Samuel Dwight)
Science
A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.
Humphrey, S. D. (Samuel Dwight)
Ambrotype; Photography
[Sidenote: PLAIN COLLODION.]
To dissolve the soluble cotton (pyroxyline), and form plain collodion,
proceed as follows:
Take of
Sulphuric ether (concentrated), 10 ounces
Alcohol, from 90 to 95 per cent., 6 "
Soluble cotton enough to give the solution a consistency such as will
allow it to flow evenly over the surface of the glass, and impart to
it quite a thick and transparent coating. If the coating is opaque, the
cotton has not been properly prepared, the acid mixture has been too weak.
_Remarks._--It is desirable for every operator to use chemicals of uniform
strength, and the better method to adopt is to employ those purchased
from some one respectable manufactory, and not take those furnished by
irresponsible and unconscientious parties. At least one-half of the
failures experienced by beginners is from want of good chemicals. It is
not economy to purchase a _cheap article_.
_Alcohol_ is an article that can be procured in almost any small village
in the United States, and is in general fit for collodion purposes. I
have used 88 per cent, in the above proportions, also the intermediate
varieties to 98 per cent., and have been quite successful; but feel
convinced that the ordinary 98, as marked (which usually stands by actual
test 95 to 97 per cent.), is preferable, except in cases where water is
employed in dissolving the iodizing salts, when I would use fully 98 per
cent.
Before concluding the subject on plain collodion, I will introduce
the account given by Mr. E. A. Hadow of his interesting and valuable
experiments, as published in _Humphrey's Journal_, Vol. VI, page 18.
"Having obtained good collodion-wool, the next point of inquiry was with
regard to the solvent; to ascertain whether the addition of alcohol
beyond what is necessary to cause the solution of the gun-cotton in
ether, were beneficial or otherwise. For this purpose ether and alcohol
were prepared perfectly pure, and mixtures were made of 1 of alcohol
to 7 of ether, 2 to 6, 3 to 5, 4 to 4 and 5 to 3. In one ounce of each
were dissolved 6 grains of gun-cotton and 4 grains of iodide of ammonium
(iodide of potassium could not be employed, since it requires a certain
amount both of water and alcohol to keep it in solution); they were then
compared, using a 35-grain solution of nitrate of silver, both by pouring
on separate glasses, and likewise by covering two halves of a plate with
two samples, as in examining the gun cottons, thus placing them under the
same circumstances during the same time; in this way the effect of adding
alcohol was very clearly perceived, since the difference between the
collodions was much greater than could have been anticipated.
Public-domain text, read in full here on John Shaqi.
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