A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper. — John Shaqi
A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.Humphrey, S. D. (Samuel Dwight)
Science
A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.
Humphrey, S. D. (Samuel Dwight)
Ambrotype; Photography
1. _By the application of heat._--A moderately strong solution of albumen
becomes opalescent and coagulates on being heated to about 150°, but a
temperature of 212° is required if the liquid is very dilute. A layer of
_dried_ albumen cannot easily be coagulated by the mere application of
heat.
2. _By addition of strong acids._--Nitric acid coagulates albumen
perfectly without the aid of heat. Acetic acid, however, acts differently,
appearing to enter into combination with the albumen, and forming a
compound soluble in warm water acidified by acetic acid.
3. _By the action of metallic salts._--Many of the salts of the metals
coagulate albumen very completely. Nitrate of silver does so; also the
bichloride of mercury. Ammoniacal oxide of silver, however, does not
coagulate albumen.
The white precipitate formed on mixing albumen with nitrate of silver is
a chemical compound of the animal matter with protoxide of silver. This
substance, which has been termed albuminate of silver, is soluble in
ammonia and hyposulphite of soda; but after exposure to light, or heating
in a current of hydrogen gas, it assumes a brick-red color, being probably
reduced to the condition of a salt of the _suboxide_ of silver. It is then
almost insoluble in ammonia, but enough dissolves to tinge the liquid
wine-red. The author is of opinion that the _red coloration_ of solution
of nitrate of silver employed in sensitizing the albumenized photographic
paper is produced by the same compound, although often referred to the
presence of sulphuret of silver.
Albumen also combines with lime and baryta; and chloride of barium has
been recommended in positive printing upon albumenized paper, probably
from this cause.
_Chemical composition of albumen._--Albumen belongs to the _nitrogenous_
class of organic substances. It also contains small quantities of sulphur
and phosphorus.
Alcohol.
Symbol, C{4}H{6}O{2}. Atomic weight, 46.
Alcohol is obtained by the careful distillation of any spirituous or
fermented liquor. If wine or beer be placed in a retort, and heat applied,
the alcohol, being more volatile than water, rises first, and is condensed
in an appropriate receiver; a portion of the vapor of water, however,
passes over with the alcohol, and dilutes it to a certain extent, forming
what is termed "spirits of wine." Much of this water may be removed by
redistillation from carbonate of potash; but in order to render the
alcohol thoroughly _anhydrous_, it is necessary to employ _quick lime_
which possesses a still greater attraction for water. An equal weight of
this powdered lime is mixed with strong alcohol of ·823, and the two are
distilled together.
_Properties of Alcohol._--Pure anhydrous alcohol is a limpid liquid, of an
agreeable odor and pungent taste; sp. gr. at 60°, ·794. It absorbs vapor
of water, and becomes diluted by exposure to damp air; boils at 173° Fahr.
It has never been frozen.
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