A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.Humphrey, S. D. (Samuel Dwight)
Science
A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.
Humphrey, S. D. (Samuel Dwight)
Ambrotype; Photography
Alcohol distilled from carbonate of potash has a specific gravity of ·815
to ·823, and contains 90 to 93 per cent, of real spirit.
The specific gravity of ordinary rectified spirits of wine is usually
about ·840, and it contains 80 to 83 per cent, of absolute alcohol.
Ammonia.
Symbol, NH{3} or NH{4}O. Atomic weight, 17.
The liquid known by this name is an aqueous solution of the volatile gas
ammonia. Ammoniacal gas contains 1 atom of nitrogen combined with three of
hydrogen: these two elementary bodies exhibit no affinity for each other,
but they can be made to unite under certain circumstances, and the result
is ammonia.
Properties of Ammonia.--Ammoniacal gas is soluble in water to a large
extent; the solution possessing those properties which are termed
alkaline. Ammonia, however, differs from the other alkalies in one
important particular--it is volatile: hence the original color of turmeric
paper affected by ammonia is restored on the application of heat. Solution
of ammonia absorbs carbonic acid rapidly from the air, and is converted
into carbonate of ammonia; it should therefore be preserved in stoppered
bottles. Besides carbonate, commercial ammonia often contains chloride of
ammonium, recognized by the white precipitate given by nitrate of silver
after acidifying with pure nitric acid.
The strength of commercial ammonia varies greatly; that sold for
pharmaceutica purposes, under the name of liquor ammoniæ, contains about
10 per cent, of real ammonia. The sp. gr. of aqueous ammonia diminishes
with the proportion of ammonia present, the liquor ammoniæ being usually
about ·936.
_Chemical Properties._--Ammonia, although forming a large class of
salts, appears at first sight to contrast strongly by composition with
the alkalies proper, such as potash and soda. Mineral bases generally
are _protoxides of metals_, but ammonia consists simply of nitrogen and
hydrogen united with oxygen. The following remarks may perhaps tend
somewhat to elucidate the difficulty:--
_Theory of Ammonium._--This theory supposes that a substance exists
possessing the properties of a metal, but different from metallic bodies
generally in being compound in structure: the formula assigned to it is
NH{4}, 1 atom of nitrogen united with 4 of hydrogen. The hypothetical
metal is termed "ammonium," and ammonia, associated with an atom of water,
may be viewed as its _oxide_; for NH{3} + HO plainly equals NH{4}O.
Thus, as potash is the oxide of _potassium_, so ammonia is the oxide of
_ammonium_.
The composition of the _salts_ of ammonia is on this view assimilated to
those of the alkalies proper. Thus, sulphate of ammonia is a sulphate of
the oxide of _ammonium_; muriate or hydrochlorate of ammonia is a chloride
of ammonium, etc.
Ammonio-Nitrate of Silver.
(_See_ Silver, Ammonio-Nitrate of.)
Aqua-Regia. (_See_ Nitro-Hydrochloric Acid.)
Baryta, Nitrate of. (_See_ Nitrate of Baryta.)
Bichloride of Mercury.
(_See_ Mercury, Bichloride of.)
Bromine.
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