A practical treatise on the manufacture of perfumery : $b comprising directions for making all kinds of perfumes, sachet powders, fumigating materials, dentrifices, cosmetics, etc., etc., with a full account of the volatile oils, balsams, resins, and other natural and artificial perfume-substances, including the manufacture of fruit ethers, and tests of their purityDeite, C. (Carl)
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A practical treatise on the manufacture of perfumery : $b comprising directions for making all kinds of perfumes, sachet powders, fumigating materials, dentrifices, cosmetics, etc., etc., with a full account of the volatile oils, balsams, resins, and other natural and artificial perfume-substances, including the manufacture of fruit ethers, and tests of their purity
Deite, C. (Carl)
Cosmetics; Perfumes; Perfumes industry
_Detection of chloroform._--An adulteration with chloroform, if
moderate, cannot always be detected by the odor and taste. In most
cases, chloroform will considerably increase the specific gravity of
the oil. Bring into a test-tube 15 drops of the suspected oil, 45 to 90
drops of alcohol, and 30 to 40 drops of dilute sulphuric acid. After
thorough shaking, add 2 or 3 shavings of zinc sheet and heat until a
vigorous evolution of hydrogen takes place. After again shaking, set
the whole aside, and heat again when the evolution of gas becomes
weaker. This heating and gentle shaking of the fluid is several times
repeated. After 20 to 25 minutes, compound the fluid with an equal
volume of cold distilled water, shake vigorously and filter through a
paper-filter moistened with water. Strongly acidulate the filtrate with
nitric acid and compound with nitrate of silver solution. If chloroform
is present, turbidity or a precipitate of chloride of silver appears.
_Detection of benzine._--An adulteration with benzine can be readily
detected only in oils specifically heavier than water. The separation
of benzine is effected by distillation from a small glass flask in the
water bath. The distillate together with an equal volume of nitric acid
of 1.5 specific gravity is gently heated in a test-tube. A too vigorous
reaction is modified by cooling in cold water, and a too sluggish
action quickened by gentle heating (dipping in warm water). If the
mixture has a yellow color, dilute it with water, shake with ether,
mix the decanted ethereal solution with alcohol and hydrochloric acid,
add some zinc and place the whole in a lukewarm place to convert the
nitrobenzol formed into aniline. After evolution of hydrogen is done,
neutralize with potash lye, shake, take off the layer of ether, let the
latter evaporate and add to the residue a few drops of calcium chloride
solution. If benzine is present, a blue-violet color reaction takes
place.
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