A practical treatise on the manufacture of perfumery : $b comprising directions for making all kinds of perfumes, sachet powders, fumigating materials, dentrifices, cosmetics, etc., etc., with a full account of the volatile oils, balsams, resins, and other natural and artificial perfume-substances, including the manufacture of fruit ethers, and tests of their purity — John Shaqi
A practical treatise on the manufacture of perfumery : $b comprising directions for making all kinds of perfumes, sachet powders, fumigating materials, dentrifices, cosmetics, etc., etc., with a full account of the volatile oils, balsams, resins, and other natural and artificial perfume-substances, including the manufacture of fruit ethers, and tests of their purityDeite, C. (Carl)
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A practical treatise on the manufacture of perfumery : $b comprising directions for making all kinds of perfumes, sachet powders, fumigating materials, dentrifices, cosmetics, etc., etc., with a full account of the volatile oils, balsams, resins, and other natural and artificial perfume-substances, including the manufacture of fruit ethers, and tests of their purity
Deite, C. (Carl)
Cosmetics; Perfumes; Perfumes industry
Adulterations with alcohol, chloroform, and benzine are quantitatively
determined by bringing a weighed quantity of the oil into a glass flask
so that it occupies about four-fifths of the volume of the flask. Place
upon the flask a cork through which has been passed a glass-tube bent
at a right angle and provided with a cylindrical glass vessel serving
as a receiver and heating in the water bath. If the distance from the
level of the oil to the angle of the glass tube in which it inclines
downwards, amounts, for instance, to 4.72 inches, and the neck of the
flask up to its angle is 2.75 inches high outside of the direct effect
of the heat of the water bath, only the above-mentioned adulterants
distill over, while the vapor of the volatile oil condenses at a
height of 2.75 inches and flows back into the flask. The distillate
is weighed and examined as to its derivation. First add one cubic
centimeter of it to two or three cubic centimeters of potassium acetate
solution of specific gravity 1.197 and shake moderately. If a clear
mixture results, alcohol alone is present. If, however, the mixture
is not clear, and the distilled fluid sinks down and collects on the
bottom of the test-tube, chloroform is very likely present, and if
it remains floating upon the acetate solution, benzine. Next bring
two to three centimeters of the distillate into a test-tube and add
a piece of sodium metal, the size of a pea. If violent foaming, _i.
e._, an evolution of gas, takes place, alcohol is certainly present,
and possibly also chloroform and benzine towards which sodium is
indifferent. However, in the presence of benzine, the sodium solution
would be colorless, and in the presence of chloroform, yellowish
and turbid. In case the sodium produces no reaction and alcohol is,
therefore, not present, add an equal volume (two to three cubic
centimeters) of anhydrous alcohol, and after moderately shaking allow
the solution of the sodium and the evolution of gas to proceed, whereby
benzine produces a nearly colorless, turbid fluid, and chloroform a
yellowish, milky one. Now dilute the fluid with an equal or double
volume of water, shake and allow the mixture to stand quietly. In the
presence of benzine a colorless, turbid layer collects on the bottom
of the fluid, while that collecting in the presence of chloroform is
yellowish. In the latter case, _i. e._, in the presence of chloroform,
the aqueous filtrate yields with lead acetate solution a white
precipitate (lead chloride and lead hydroxide). The adulterant having
thus been recognized, further particulars are learned from the specific
gravity of the oil as well as of the distillate.
Adulterations with _terpenes_ or _terpene-like fluids_, such as are
gained in the preparation of concentrated or patent oils, are difficult
to recognize. They may be detected by the specific gravity, the
terpenes being, as a rule, specifically lighter, their specific gravity
varying between 0.840 and 0.870.
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