A practical treatise on the manufacture of perfumery : $b comprising directions for making all kinds of perfumes, sachet powders, fumigating materials, dentrifices, cosmetics, etc., etc., with a full account of the volatile oils, balsams, resins, and other natural and artificial perfume-substances, including the manufacture of fruit ethers, and tests of their purityDeite, C. (Carl)
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A practical treatise on the manufacture of perfumery : $b comprising directions for making all kinds of perfumes, sachet powders, fumigating materials, dentrifices, cosmetics, etc., etc., with a full account of the volatile oils, balsams, resins, and other natural and artificial perfume-substances, including the manufacture of fruit ethers, and tests of their purity
Deite, C. (Carl)
Cosmetics; Perfumes; Perfumes industry
Oil of sassafras varies in color from colorless to yellow and red.
Its taste is pungent and aromatic, being agreeable to most persons.
It has a pleasant odor resembling that of fennel, and is heavier than
water, its specific gravity being 1.08 to 1.09. It is soluble in 4 to 5
parts of alcohol of 0.85 specific gravity, and consists of a mixture of
various oils, among which is safrene (C_{10}H_{16}), a dextrorotatory
terpene which boils between 311° and 314.6° F. By strongly cooling in
a cold mixture, safrol, a crystallizing stearoptene of the composition
C_{10}H_{10}O_{2}, is separated. Safrol is the chief constituent of
sassafras oil. It is obtained in abundance by cooling, at a temperature
of 13° F., the portion boiling between 442.4° and 455° F. It melts at
46.4° F., and at a medium temperature forms a colorless clear oil of
pungent taste, characteristic odor, and specific gravity 1.104. When
the crystals have been heated to above 158° F., they congeal only after
remaining for weeks at a temperature below 32° F., but on being melted
at 68° F., the fluid mass again congeals readily on cooling. The safrol
is neutral, optically inactive, boils at 449.6° F., and is soluble in
alcohol and ether. Sassafras oil is said to be frequently adulterated
with oil of turpentine, which is, however, readily detected by the
energetic reaction and by distilling a sample of the suspected oil.
Safrol is very suitable for perfuming ordinary soaps. It has in a
still higher degree than camphor oil the property of removing the
disagreeable odor of some fats, while at the same time it imparts to
the soaps an aromatic, refreshing odor. As a rule 8 to 11 ozs. are
used for 220 lbs. of soap; but if it shall at the same time serve for
removing the disagreeable odor of low quality fats, especially those
extracted with bisulphide of carbon or benzine, it is advisable to
take 2.2 lbs., or still better, 4.4 lbs. for 220 lbs. of soap. In this
case the safrol should be added to the fat after melting and before
saponification and thoroughly mixed with it by stirring. An excellent
perfume for ordinary soaps is a mixture of safrol and citronella oil,
it being at any rate preferable to oil of mirbane.
The standard of value for safrol is its specific gravity, which should
not be below 1.104 at 59° F. Specifically lighter kinds contain camphor
oil and other impurities.
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