A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
NICKEL AND COBALT.
* * * * *
Mineral. Millerite
Formula. NiS.
Behavior
(1) in glass-bulb. --
(2) in open tube. Evolves SO^{2}.
(3) on charcoal. Fuses with much ebullition to a magnetic bead.
(4) in forceps. --
(5) in borax. The roasted mineral gives a nickel reaction,
slightly modified by small quantities of iron
and copper.
(6) in mic. salt. As in borax.
(7) with carb. soda. Fuses to a slaggy mass, which on silver gives
the sulphur reaction.
(8) Special reactions. --
* * * * *
Mineral. Coppernickel
Formula. Ni^{2}As.
Behavior
(1) in glass-bulb. Gives off a little AsO^{3}.
(2) in open tube. Gives off much AsO^{3} and some SO^{2} and falls
to powder.
(3) on charcoal. Fuses to a magnetic bead, with the evolution of
arsenic, which colors the flame blue.
(4) in forceps. --
(5) in borax. The arsenical bead obtained by fusing the
mineral on charcoal, if fused upon the same
support with borax successively added and
removed, gives firstly an iron reaction, then
cobalt if present, and lastly nickel.
(6) in mic. salt. If the residual bead which has been treated with
borax be further treated with microcosmic salt,
the nickel reaction will be obtained and
sometimes a slight copper reaction.
(7) with carb. soda. --
(8) Special reactions. Affords a sublimate of metallic arsenic when
treated with cyanide of potassium.
* * * * *
Mineral. Smaltine
Formula. CoAs.
Behavior
(1) in glass-bulb. When strongly heated generally evolves metallic
arsenic.
(2) in open tube. Gives a crystalline sublimate of AsO^{3}. Also
some SO^{2}.
(3) on charcoal. Gives off fumes of arsenic, and fuses to a dark
grey magnetic bead, very brittle, colors flame
blue.
(4) in forceps. --
(5) in borax. As the preceding, but the cobalt being in large
excess requires some time for its perfect
oxidation, before the nickel reaction is
exhibited.
(6) in mic. salt. Gives the cobalt reaction, and after the cobalt
has been, removed that of nickel.
(7) with carb. soda. --
(8) Special reactions. As the preceding.
* * * * *
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