A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
(6) in mic. salt. As in borax, but the reduction of the nickel is
more difficult than in the latter flux.
(7) with carb. soda. As glance cobalt.
(8) Special reactions. As copper nickel, but the amount of arsenic is
usually very small.
* * * * *
Mineral. Emerald nickel
Formula. [.Ni]^{3}[..C] + 6[.H].
Behavior
(1) in glass-bulb. Gives off much water and turns black.
(2) in open tube. --
(3) on charcoal. --
(4) in forceps. --
(5) in borax. Dissolves with much effervescence and gives the
nickel reaction.
(6) in mic. salt. As in borax.
(7) with carb. soda. Forms a slaggy mass.
(8) Special reactions. In warm dilute HCl dissolves with much
effervescence.
* * * * *
Mineral. Cobalt Bloom
Formula. [.Co]^{3}[.....As] + 8[.H].
Behavior
(1) in glass-bulb. Gives off water.
(2) in open tube. --
(3) on charcoal. Evolves arsenical fumes and in the reducing
flame fuses to a dark grey bead of arsenide of
cobalt.
(4) in forceps. In the point of the blue flame fuses and colors
the outer flame blue (As).
(5) in borax. Gives the cobalt reaction.
(6) in mic. salt. As in borax.
(7) with carb. soda. --
(8) Special reactions. Gives off arsenic with cyanide of potassium in
glass tube.
* * * * *
Mineral. Earthy cobalt
Formula. [.Mn],[.Co],[.Cu],[.Fe],[.H], etc.
Behavior
(1) in glass-bulb. Gives off water.
(2) in open tube. --
(3) on charcoal. Emits a slight smell of arsenic, but does not
fuse.
(4) in forceps. Colors the flame blue.
(5) in borax. In oxidizing flame gives the cobalt reaction
which obscures those of [.Mn], [.Cu], etc. In
reducing flame occasionally gives the [.Cu]
reaction.
(6) in mic. salt. As in borax. If a saturated bead be treated on
charcoal with tin in the reducing flame for a
few seconds, the [.Cu] reaction is sometimes
obtained.
(7) with carb. soda. Forms an infusible mass.
(8) Special reactions. With carbonate of soda and nitre on platinum
foil, gives a strong manganese reaction.
* * * * *
ZINC.
* * * * *
Mineral. Zincblende
Formula. ZnS.
Behavior
(1) in glass-bulb. Decrepitates strongly.
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