A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
(1) in glass-bulb. Sometimes decrepitates, fuses, and when very
strongly heated, gives a red sublimate of
[,,,Sb] with [...Sb], also sometimes a black
sublimate of [,Hg] and occasionally [,,,As].
(2) in open tube. Fuses and gives off thick fumes of SbO^{3} and
SO^{2}, also generally AsO^{3}, leaving a black
infusible residue. If Hg be present, it is
sublimed and condenses in the tube in small
drops.
(3) on charcoal. Fuses to a bead, which fumes strongly and
incrusts the charcoal with SbO^{3}, and
sometimes ZnO, which cannot be volatilized.
Emits a strong smell of arsenic.
(4) in forceps. --
(5) in borax. The residue obtained on charcoal thoroughly
roasted gives a copper reaction, and when the
latter has been removed by reduction upon
charcoal, an iron reaction.
(6) in mic. salt. As in the preceding.
(7) with carb. soda. With this flux and a little borax yields a bead
of metallic copper; on silver, the alkaline mass
gives a sulphur reaction.
(8) Special reactions. If the copper bead obtained by fusing upon
carbonate of soda be cupelled with assay lead, a
silver bead will be obtained. Or if dissolved in
nitric acid and a drop or two of HCl added, a
white precipitate of AgCl will be formed, which
may be collected and reduced with carbonate of
soda upon charcoal.
* * * * *
Mineral. Tennatite
Formula. ([,Cu=][,Fe=])^{4}[,,,As].
Behavior
(1) in glass-bulb. Decrepitates occasionally and gives a red
sublimate of [,,,As].
(2) in open tube. Evolves [..S] and [...As], which condense and
form a white sublimate.
(3) on charcoal. Fuses to a magnetic bead giving of arsenical and
sulphurous fumes.
(4) in forceps. --
(5) in borax. As the preceding.
(6) in mic. salt. As the preceding.
(7) with carb. soda. Yields a copper bead and metallic iron in the
form of a dark grey powder. The fused alkali
gives the sulphur reaction.
(8) Special reactions. --
* * * * *
Mineral. Bournonite
Formula. ([,Pb]^{2}[,Cu=])[,,,Sb].
Behavior
(1) in glass-bulb. Decrepitates giving off sulfur and, when
strongly heated, [,,,Sb] and [...Sb].
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