A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
(_c._) _Platinum Wire._--As the color of the flame cannot be well
discerned when the substance is supported upon charcoal, in
consequence of the latter furnishing false colors, by its own
reflection, to the substances under examination, we use platinum wire
for that purpose, when we wish to examine those substances which give
indications by the peculiar color which they impart to fluxes. The
wire should be about as thick as No. 16 or 18 wire, or about 0.4
millimetre, and cut into pieces about from two and a half to three
inches in length. The end of each piece is crooked. In order that
these pieces should remain clear of dirt, and ready for use, they
should be kept in a glass of water. To use them, we dip the wetted
hooked end into the powdered flux (borax or microcosmic salt) some of
which will adhere, when we fuse it in the flame of the blowpipe to a
bead. This bead hanging in the hook, must be clear and colorless.
Should there not adhere a sufficient quantity of the flux in the first
trial to form a bead sufficiently large, the hook must be dipped a
second time in the flux and again submitted to the blowpipe flame. To
fix the substance to be examined to the bead, it is necessary, while
the latter is hot, to dip it in the powdered substance. If the hook is
cold, we moisten the powder a little, and then dip the hook into it,
and then expose it to the oxidation flame, by keeping it exposed to a
regular blast until the substance and the flux are fused together, and
no further alteration is produced by the flame.
The platinum wire can be used except where reduction to the metallic
state is required. Every reduction and oxidation experiment, if the
results are to be known by the color of the fluxes, should be effected
upon platinum wire. At the termination of the experiment or
investigation, if it be one, to, clean the wire, place it in water,
which will dissolve the bead.
(_d._) _Platinum Foil._--For the heating or fusing of a substance,
whereby its reduction would be avoided, we use platinum foil as a
support. This foil should be of the thickness of good writing paper,
and from two and a half to three inches long, by about half an inch
broad, and as even and smooth as possible. If it should become injured
by long use, cut the injured end off, and if it should prove too short
to be held with the fingers, a pair of forceps may be used to grasp
it, or it may be placed on a piece of charcoal.
(_e._) _Platinum Spoon._--When we require to fuse substances with the
acid sulphate of potash, or to oxidize them by detonation with nitrate
of potash, whereby we wish to preserve the oxide produced, we
generally use a little spoon of platinum, about from nine to fifteen
millimetres[1] in diameter, and shaped as represented in Fig. 7. The
handle of this spoon is likewise of platinum, and should fit into a
piece of cork, or be held with the forceps.
[1] The French millimetre is about the twenty-fifth part of an
English inch.
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