A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations — John Shaqi
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
10. _Tin._--This metal is used in the form of foil, cut into strips
about half an inch wide. Tin is very susceptible of oxidation, and
therefore deprives oxidized substances of their oxygen very quickly,
when heated in contact with them. It is employed in blowpipe analysis,
for the purpose of producing in glass beads a lower degree of
oxidation, particularly if the substance under examination contains
only a small portion of such oxide. These oxides give a characteristic
color to the bead, and thus are detected. The bead is heated upon
charcoal in the reduction flame, with a small portion of the tin,
whereby some of the tin is melted and mixes with the bead. The bead
should be reduced quickly in the reduction flame, for by continuing
the blast too great a while, the oxide of tin separates the other
oxides in the reduced or metallic state, while we only require that
they shall only be converted into a sub-oxide, in order that its
peculiar color may be recognized in the bead. The addition of too much
tin causes the bead to present an unclean appearance, and prevents
the required reaction.
11. _Silica_ (SiO^{3}).--This acid does not even expel carbonic acid
in the wet way, but in a glowing heat it expels the strongest volatile
acids. In blowpipe analysis, we use it fused with carbonate of soda to
a bead, as a test for sulphuric acid, and in some cases for phosphoric
acid. Also with carbonate of soda and borax, for the purpose of
separating tin from copper.
Finely powdered quartz will answer these purposes. If it cannot be
procured, take well washed white sand and mix it with two parts of
carbonate of soda and two parts of carbonate of potassa. Melt the
materials together, pound up the cooled mass, dissolve in hot water,
filter, add to the filtrate hydrochloric acid, and evaporate to
dryness. Moisten the dry residue with hydrochloric acid, and boil in
water. The silica remains insoluble. It should be washed well, dried,
and heated, and then reduced to powder.
12. TEST-PAPERS.--(_a._) _Blue, Litmus Paper._--Dissolve one part of
litmus in six or eight parts of water, and filter. Divide the filtrate
into two parts. In one of the parts neutralize the free alkali by
stirring it with a glass rod dipped in diluted sulphuric acid, until
the fluid appears slightly red. Then mix the two parts together, and
draw slips of unsized paper, free from alkali, such as fine filtering
paper. Hang these strips on a line to dry, in the shade and free from
floating dust. If the litmus solution is too light, it will not give
sufficient characteristic indications, and if too dark it is not
sensitive enough. The blue color of the paper should be changed to
red, when brought in contact with a solution containing the minutest
trace of free acid; but it should be recollected that the neutral
salts of the heavy metals produce the same change.
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