A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
(_b._) _Red Litmus Paper._--The preparation of the red litmus paper is
similar to the above, the acid being added until a red color is
obtained. Reddened litmus paper is a very sensitive reagent for free
alkalies, the carbonates of the alkalies, alkaline earths, sulphides
of the alkalies and of the alkaline earths, and alkaline salts with
weak acids, such as boracic acid. These substances restore the
original blue color of the litmus.
(_c._) _Logwood Paper._--Take bruised logwood, boil it in water,
filter, and proceed as above. Logwood paper is a very delicate test
for free alkalies, which impart a violet tint to it. It is sometimes
used to detect hydrofluoric acid, which changes its color to yellow.
All the test-papers are to be cut into narrow strips, and preserved in
closely stopped vials. The especial employment of the test-papers we
shall allude to in another place.
B. ESPECIAL REAGENTS.
13. _Fused Boracic Acid_ (BO^{3}).--The commercial article is
sufficiently pure for blowpipe analysis. It is employed in some cases
to detect phosphoric acid, and also minute traces of copper in lead
compounds.
14. _Fluorspar_ (CaFl^{2}).--This substance should be pounded fine and
strongly heated. Fluorspar is often mixed with boracic acid, which
renders it unfit for analytical purposes. Such an admixture can be
detected if it be mixed with bisulphate of potassa, and exposed upon
platinum wire to the interior or blue flame. It is soon fused, the
boracic acid is reduced and evaporated, and by passing through the
external flame it is reoxidized, and colors the flame green. We use
fluorspar mixed with bisulphate of potassa as a test for lithia and
boracic acid in complicated compounds.
15. _Oxalate of Nickel_ (NiO, [=]O).--It is prepared by dissolving the
pure oxide of nickel in diluted hydrochloric acid. Evaporate to
dryness, dissolve in water, and precipitate with oxalate of ammonia.
The precipitate must be washed with caution upon a filter, and then
dried. It is employed in blowpipe analysis to detect salts of potassa
in the presence of sodium and lithium.
16. _Oxide of Copper_ (CuO).--Pure metallic copper is dissolved in
nitric acid. The solution is evaporated in a porcelain dish to
dryness, and gradually heated over a spirit-lamp, until the blue color
of the salt has disappeared and the mass presents a uniform black
color. The oxide of copper so prepared must be powdered, and preserved
in a vial. It serves to detect, in complicated compounds, minute
traces of chlorine.
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