A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
In the reduction flame no change is visible if the quantity of iron be
small. By the addition of more iron, the hot bead appears red, and
while cooling, changes to yellow, then green, and, when cold, is of a
dull red. By fusing the bead on charcoal with a small addition of tin,
it exhibits, while cooling, a bluish-green color, but, when cold, is
colorless.
The oxides of iron are not dissolved in the oxidation flame by fusion
with carbonate of soda. By ignition with soda upon charcoal in the
reduction flame, they are absorbed and reduced to the metallic state.
Cut out this portion of the charcoal; grind it with the addition of
some water in an agate mortar, for the purpose of washing off the
carbon particles, when the iron will remain as a grey magnetic powder.
(_b._) _Cobalt_ (Co) occurs in combination with arsenic and sulphur,
and associated with nickel and iron. It is found occasionally in
combination with selenium, and there are a traces of it in meteoric
iron. In the metallic state it is of a light, reddish-grey color,
rather brittle, and only fusible at a strong white heat; at common
temperatures it is unalterable by air or water. At a red heat, it
oxidizes slowly and decomposes water; at a white heat it burns with a
red flame. Cobalt is soluble in dilute sulphuric or hydrochloric acid
by the aid of heat, whereby hydrogen is eliminated. These solutions
have a fine red color.
_Protoxide of Cobalt_ (CoO).--It is an olive-green powder, but, by
exposure to the air, it becomes gradually brown. Its hydrate is a rich
red powder. The solution of its salts is red, but the aqueous solution
is often blue.
When heated in the oxidation flame, the protoxide is converted into
the black proto-sesquioxide (CoO + Co^{2}O^{3}). In the reduction
flame it shrinks and is reduced without fusion to the metallic state.
It is now attracted by the magnet and acquires lustre by compression.
Borax dissolves it in the oxidation flame, and produces a clear,
intensely colored blue bead, which remains transparent and of the same
beautiful blue when cold. This blue is likewise manifest even if the
bead be heated intermittingly. If the cobalt exists in considerable
quantity, the color of the bead is so intense as to appear almost
black.
This reaction of cobalt is so characteristic and sensitive that it can
detect a minute trace.
With microcosmic salt the same reaction is exhibited, but not so
sensitive, nor is the bead so intensely colored when cold as that with
borax.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account