A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
By fusion with carbonate of soda upon a platinum wire, with a very
small portion of cobalt, a bright red colored mass is produced which
appears grey, or slightly green when cold. By fusion upon platinum
foil the fused portion floats down from the sides, and the foil is
coated around the undissolved part, with a thin, dark-red sublimate.
When fused upon charcoal, and in the reduction flame, it is reduced
with soda to a grey powder, which is attracted by the magnet, and
exhibits the metallic lustre by compression.
_Sesquioxide of Cobalt_ (Co^{2}O^{3}).--It is a dark brown powder. Its
hydrate (2HO + Co^{2}O^{3}) is a brown powder. It is soluble only in
acetic acid as the acetate of the sesquioxide. All other acids
dissolve its salts to protoxide, the hydrochloric acid producing
chloric gas. By ignition in the oxidation flame, it is converted into
the proto-sesquioxide (CoO + Co^{2}O^{3}) and produces with reagents
before the blowpipe the same reactions as the protoxide.
(_c._) _Nickel_ (Ni).--This metal occurs invariably associated with
cobalt, and in analogous combinations, chiefly as the arsenical
nickel. In the metallic state it is greyish, silver-white, has a high
lustre, is hard, and malleable both cold and hot. At common
temperatures, it is unalterable either in dry or moist air. When
ignited, it tarnishes. It is easily dissolved by nitric acid, but very
slowly by dilute sulphuric or hydrochloric acid, producing hydrogen.
_Protoxide of Nickel _(NiO).--It is in the form of small greyish-black
octahedrons, or a dark, greenish-grey powder. Its hydrate is a green
powder. Both are unalterable in the air, and are soluble in nitric,
sulphuric, and hydrochloric acids, to a green liquid. The protoxide is
the base of the salts of nickel, which in the anhydrous state are
yellow, and when hydrated are green. The soluble neutral salts change
blue litmus paper to red. By ignition in the oxidation flame,
protoxide of nickel is unaltered. In the reduction flame and upon
charcoal, it becomes reduced, and forms a grey adherent powder, which
is infusible, and presents the metallic lustre by compression, and is
magnetic. Borax dissolves it in the oxidation flame very readily to a
clear bead, of a reddish-violet or dark yellow color, but yellow or
light red when cold. If there is but a small quantity of the oxide
present, it is colorless. If more of the oxide be present, the bead is
opaque and dark brown, and appears, while cooling, transparent and
dark red. By the addition of a salt of potassa (the nitrate or
carbonate) a blue or a dark purple colored bead is produced. The borax
bead, in the reduction flame, is grey, turbid, or completely opaque
from the reduced metallic particles. After a continued blast, the bead
becomes colorless, although the particles are not fused. If the nickel
contains cobalt, it will now be visible with its peculiar blue color.
Upon charcoal, and by the addition of some tin, the reduction of the
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