A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
The strip should be annealed during the rolling and again
at the finish.
~Parting.~--The thin sheet of metal is dropped into hot dilute nitric
acid and boiled for five or six minutes after the brisk action of the
acid on the metal has ceased. At this stage nearly all the silver has
gone into solution as nitrate of silver and the acid is charged with
this salt. This acid is poured off and the residual metal is again
boiled for from 20 to 30 minutes with a second lot of stronger acid.
This leaves the gold almost pure, though it may still retain from .05 to
.1 per cent. of silver. Treatment with the first acid only would
probably leave three or four times as much.
The _nitric acid_ used should be free from hydrochloric, sulphuric,
iodic and telluric acids. In testing it for the first of these add
nitrate of silver and dilute with distilled water; there should be no
turbidity. In testing for the others evaporate three lots in dishes over
a water-bath. Test one for sulphates by adding water and barium
chloride. Test another for iodates by taking up with a little water,
adding a few drops of starch paste and then dilute sulphurous acid
solution a little at a time; there should be no blue colour. Test the
third for tellurium by heating with 1 c.c. of strong sulphuric acid
until dense fumes come off; allow to cool considerably; a piece of tin
foil added to the warm acid develops a fine purple colour if only a
trace of tellurium is present.
The presence of lower oxides of nitrogen, which impart a brown colour to
the acid, is objectionable; they, however, are removed by boiling the
diluted acid before using it for parting. It is usual to keep a stock of
the acid suitably diluted to the two strengths required for the parting.
These are known as the parting acids. The _first parting acid_ is the
weaker and is used in the first attack on the metal. The specific
gravity generally recommended for it is about 1.2. It may be prepared
either by diluting the strong acid with about its own volume of
distilled water, or by suitably diluting the second parting acid which
has been already used in an assay; the small proportion of silver this
contains is not harmful for this purpose. The _second parting acid_ has
a specific gravity of about 1.3, and may be made by diluting the strong
acid with half its volume of distilled water.
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