A Text-book of Paper-makingCross, C. F. (Charles Frederick)
Science
A Text-book of Paper-making
Cross, C. F. (Charles Frederick)
Paper industry; Papermaking
Cellulose di-nitrate, C_{18}H_{13}O_{8} (NO_{3})_{2} always results as
the final product of the action of alkalis on the other nitrates, and
also from the action of hot, somewhat dilute, nitric acid on cellulose.
The di-nitrate is very soluble in ether-alcohol, acetic ether, and in
absolute alcohol. Further action of alkalis on the di-nitrate results
in a complete decomposition of the molecule, some organic acids and
tarry matters being formed. The reactions and resolution products of
this body have, however, been but slightly studied, and apparently not
at all with the view to elucidate anything respecting the constitution
of cellulose itself.
_Cellulose and Chlorine._—Dry chlorine gas has no action upon
cellulose, but the presence of water determines an indirect oxidising
action. This oxidising action results from the decomposition of water
by chlorine with formation of hydrochloric acid and liberation of
oxygen. The reaction, however, can only take place in the presence of
light.
_Cellulose and Oxygen._—When cotton is exposed for some time to the
action of a solution of bleaching powder, in the cold, and with access
of air, e.g. when a piece of white calico is moistened with the
solution, squeezed out and exposed to the air, it is found to undergo
gradual disintegration accompanied by a change in composition, and an
elementary {11} analysis of the product shows it to contain less carbon
and more oxygen than the original cellulose. The following percentage
numbers indicate the composition of these oxidised derivatives of
cellulose, and the progress of the oxidation:—
12 hours’ exposure. 24 hours’ exposure.
C 43·78 43·47 43·00 42·90
H 5·85 6·13 6·28 6·18
O 50·37 50·40 50·72 50·92
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