A Text-book of Paper-makingCross, C. F. (Charles Frederick)
Science
A Text-book of Paper-making
Cross, C. F. (Charles Frederick)
Paper industry; Papermaking
Other oxidising agents produce similar results; even by exposure to
air and light, cellulose is slowly converted into these oxidised
derivatives.[2] From their mode of formation, they have been termed
oxycelluloses, and to distinguish them from a series of more
highly oxidised derivatives, produced by the action of nitric acid
upon cellulose, which they nevertheless resemble in many of their
characteristics, the prefix α is employed. The following are the
distinguishing features of the α oxycelluloses as represented by the
more extreme of the above mentioned products. It reduces Fehling’s
solution at the boiling temperature, and the cuprous oxide is deposited
upon the fibre in a state of intimate union, producing the effect of
an orange dye. It attracts the basic colouring matters from their
solutions and is dyed to a full shade, the depth of colour being
proportionate to the amount of oxidation to which the cellulose has
been subjected. See also p. 43. Treated with a warm solution of
phenylhydrazine salts in water, it is coloured a bright lemon-yellow.
Its most remarkable property is its attraction for the vanadium
compounds, which is so powerful that combination may be proved to
take place when this element in the form of chloride is presented to
the oxycellulose in an aqueous solution containing not more than 1 in
1,000,000,000,000 parts.
[Footnote 2: Witz. Bull. Soc. Ind. Rouen, _X._ 416, and _XI._ 189.]
The β oxycellulose resulting, as already indicated, from the
action of dilute nitric acid upon cellulose, will be subsequently
considered, under the head of the decompositions of cellulose, to
which the reaction which we have been considering may be regarded as
transitional. {12}
_Decomposition of Cellulose._—_Acids._—Of the decomposition of
cellulose by artificial means, i.e. by the action of reagents, the
most important are those which disclose the relationship which it
bears to the group of so-called carbo-hydrates. Cellulose is, indeed,
a highly _elaborated_ carbo-hydrate, differing from dextrin and
starch, not so much in its essential constitution as in the molecular
arrangement which has been impressed upon it in and through the life of
the plant. There are numerous observations in biological science which
demonstrate the close connection, and in many cases the physiological
equivalence of the members of this natural group, which includes the
sugars, dextrin, starches, and cellulose. The following facts show the
constitutional or chemical ties which underlie their interdependence.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account