A Text-book of Paper-makingCross, C. F. (Charles Frederick)
Science
A Text-book of Paper-making
Cross, C. F. (Charles Frederick)
Paper industry; Papermaking
_Amyloid._—When cotton is treated with 30 times its weight of sulphuric
acid somewhat diluted (1 part H_{2}O, 4 parts H_{2}SO_{4}) it quickly
dissolves, the solution being at first gelatinous, becoming afterwards
syrupy. On pouring this solution into water, a white flocculent
precipitate is formed, consisting of a substance closely resembling the
cellulose from which it is derived, differing, indeed, only in being
amorphous, and in being coloured blue by iodine. This substance, from
its resemblance to starch, has been called _amyloid_. When sufficiently
dehydrated it constitutes a swollen starchy mass, which dries to a
brittle transparent solid. This transformation appears to consist in a
simple hydration of the cellulose molecule, thus:—
Cellulose. Amyloid.
2 (C_{6}H_{10}O_{5}) + H_{2}O = C_{12}H_{22}O_{11}.
The modification of cellulose, which occurs on the conversion of
unsized paper into the so-called parchment paper, by exposure for a
short time to the action of strong sulphuric acid, and subsequent
washing and drying, consists doubtless in a superficial conversion of
the cellulose into _amyloid_, or a body closely resembling it.
_Hydracellulose._—Closely related in composition to the above {13}
described amyloid, is the substance called hydracellulose, into which
cellulose is converted by exposure for some time to the action of
moderately strong sulphuric, or hydrochloric acids (sp. gr. 1·35).
This substance is also formed by the action of very weak acids, if the
exposure of the cellulose be sufficiently prolonged. Its formation is
accompanied by the complete disintegration of the cellulose. If the
action of strong sulphuric acid be prolonged, a further modification
ensues, dextrin or sugar being formed. These products have not been
sufficiently studied to have established their exact identity with
any of the substances known under these group-names. The dextrin has
a close resemblance to the dextrin obtained from starch; the sugar
is susceptible of fermentation; but beyond this nothing specific is
known of these bodies. Their general properties, however, and mode of
formation, sufficiently establish the fact that cellulose itself is
constituted of similar molecules.
The action of zinc chloride solution upon cellulose is similar to that
of sulphuric acid.
Cellulose in contact with iron, and in presence of air and moisture, is
converted into a sugar and a gummy substance, which latter is converted
into a sugar on boiling with dilute acids. Oxidised by potassium
permanganate or bichromate in presence of acetic acid, it is converted
into glucose, dextrin, and formic acid.
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