A Text-book of Paper-makingCross, C. F. (Charles Frederick)
Science
A Text-book of Paper-making
Cross, C. F. (Charles Frederick)
Paper industry; Papermaking
[Footnote 4: The action of alkaline substances dissolved from the
glass must be taken into account in this decomposition.]
_Decomposition by means of ferments, &c._—The soluble ferment of the
foxglove has been found to convert cellulose into glucose and dextrin.
The fluid from the vermiform appendix of the rabbit has also been found
to digest cellulose with liberation of marsh gas and formation of a
soluble compound which reduces cupric oxide in alkaline solution.
_Humus._—In the natural decay of cellulosic structures a large quantity
of marsh gas is formed, and solid products are formed, which are
usually known as humic or ulmic substances. These bodies are amorphous,
are largely dissolved by alkaline solutions, and are attacked by
chlorine gas in presence of moisture, yielding yellow coloured
chlorinated derivatives whose composition has a general resemblance to
the chlorinated compounds obtained from the compound celluloses, to be
hereafter described.
The most important part which ulmic substances play in the economy of
nature, is in the composition of soils. It is doubtful whether they
act directly as fertilisers, but by their action upon the mineral
constituents of soils they contribute to the supply of these necessary
elements of growth to the plant.
_Synthesis of Cellulose._—A transformation of certain soluble
carbo-hydrates into cellulose, which may be regarded as a proximate
synthesis of cellulose, has recently been brought to light. This is
set up spontaneously in beet-juice, and results in the formation of
a hard white substance, insoluble in boiling dilute potash, soluble
in the ammonio-copper reagent, converted by sulphuric acid into
dextrin and sugar, and by nitric acid into oxalic acid. On adding
some of these cellulose lumps to a solution of pure cane-sugar, a
further transformation of the saccharose into the same substance is
brought about. At the same time there is simultaneously produced a
gummy substance, which is precipitated by {16} alcohol as a white
amorphous caoutchouc-like mass, of the same composition as cellulose,
but swelling up with water, and otherwise differing in its physical
properties from cellulose. This latter substance is also formed by the
action of diastaste upon a solution of saccharose.
The process of cellulosic fermentation may be represented by the
equation:
n. (C_{12}H_{22}O_{11}) = n. (C_{6}H_{10}O_{5}) + n. (C_{6}H_{12}O_{6})
Saccharose. Cellulose. Glucose.
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