A Text-book of Paper-makingCross, C. F. (Charles Frederick)
Science
A Text-book of Paper-making
Cross, C. F. (Charles Frederick)
Paper industry; Papermaking
A similar transformation takes place under the influence of certain
fatty seeds, e. g. those of rape and colza; and it is probable that
the formation of cellulose in living plants may take place at the
expense of saccharose and under the influence of ferments. In support
of this it has been established that in the sugar-cane, the formation
of wood—i.e. cellulose—is accompanied _pari passu_ by a decrease
in saccharose. More recently, A. Brown (_Chem. Soc. Journ._, 432,
1886) has investigated the formation of cellulose by the “vinegar
plant” growing in solutions of the carbo-hydrates, e. g. dextrose in
yeast-water. The cells elaborate an extra-cellular fibrin, which acts
as a “cell-collecting medium,” and they possess therefore a two-sided
activity, i.e. the property above mentioned, in addition to their
strictly fermentative activity. The cellulose film in question was
found to contain 50 to 60 per cent. of pure cellulose. It is noteworthy
that in a solution of levulose the growth of the “plant” is unattended
by fermentative action, 33 per cent. of the substance being, on the
other hand, transformed into cellulose.
_Modifications of Cellulose in the Plant. Compound Celluloses._—It has
been already stated that cellulose occurs in nature for the most part
in a form different from that in which we have hitherto considered it,
viz. either combined or mixed with other substances which are of such
a nature that they may be removed by a chemical process, more or less
simple. One of the most characteristic of these modified celluloses
constitutes the jute fibre, the isolated bast of an Indian plant,
{17} which has an enormous industrial application for the coarser
textile purposes. The chemistry of jute throws light on the course of
lignification, the process by which cellulose is modified into wood,
and in studying it in preference to wood we have the advantage of
studying a simple tissue.
Like cellulose, jute dissolves in cuprammonia, and is similarly acted
upon by the concentrated acids. By nitric acids it is converted into
nitric ethers, which are yellow coloured, but in other respects closely
resemble the pyroxylins. They are entirely soluble in acetone.
Jute differs from cellulose in the following respects: its percentage
composition (excluding ash) is
C 47·0 48·0 per cent.
H 5·9 5·7 „
O 47·1 46·3 „
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