A Text-book of Paper-makingCross, C. F. (Charles Frederick)
Science
A Text-book of Paper-making
Cross, C. F. (Charles Frederick)
Paper industry; Papermaking
Pseudo-carbons are obtained as products of the action of various
reagents upon the celluloses, and other of the so-called
carbo-hydrates. These reagents, such as sulphuric acid, act in virtue
of their dehydrating power; and the recognition of this fact, together
with the supposed “carbonaceous” {25} character of the product,
led to the erroneous conclusion that the carbohydrates are in such
decompositions simply resolved into carbon and water; a conclusion
which seems to derive additional warrant from the peculiar numerical
relationship which exists between the C, H, O atoms of all the members
of the group. Their relation is expressed in the general formula C_{n}
H_{2(n−m)} O_{(n−m)}, and in the somewhat misleading term carbohydrate,
which is applied to the whole group. We now know that the removal of
water from these bodies by the action of dehydrating agents—including
heat—follows the ascertained laws of chemical dehydration, involving
molecular condensations and rearrangement, and that the pseudo-carbons
are the extreme terms of a series of such condensations or cumulative
resolutions. The matter, however, is not as yet sufficiently
investigated to enable us to state with any preciseness the mechanism
of these changes. Still this general statement will enable us to avoid
many of the erroneous views which have existed on the subject, and in a
measure to anticipate the results of future investigation.[6]
[Footnote 6: It is worthy of mention that by the action of
chlorine in presence of water, and by the action of concentrated
nitric acid upon the cannel coals, substitution derivatives are
formed resembling those obtained by the action of these reagents
respectively upon the ligno-celluloses.]
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