A Text-book of Paper-makingCross, C. F. (Charles Frederick)
Science
A Text-book of Paper-making
Cross, C. F. (Charles Frederick)
Paper industry; Papermaking
_General conclusions._—The aldehydic character of the group of
ligno-celluloses is typical of the constituents of plant tissues
generally, and is, there can be no doubt, extended to the celluloses.
Indeed the evidence of biological observation goes to show that the
ligno-celluloses are formed, by a process of chemical modification,
from some more purely cellulosic tissue, which preceded it, and
with this modification there is, nevertheless, a retention of the
general features of the original cellulose. In the domain of animal
chemistry, recent investigation has also shown that the development
of proteid tissues finds its chemical expression in their aldehydic
characteristics, or as it has been put, the immediate physical cause
of life is to be found in the _chemical tension_ of aldehydes. The
meaning of this expression will be readily grasped on {26} reference
to the properties of the aldehydes as a group; their power of combining
with oxygen; of uniting by their own molecules, to polymerise; of
uniting by way of dehydration; of combining with the aromatic alcohols;
a consensus of properties which shows them to possess an activity
surpassing that of any other group of compounds. The evidence of
biology, added to our knowledge of the properties of these substances,
would lead us therefore to define cellulose as a condensed aldehyde
allied to the sugars, and likewise containing alcoholic OH groups; and
ligno-cellulose a compound cellulose, containing a cellulose nucleus or
residue so combined with certain groups which may be included in the
term _non-cellulose_, that it yields, under the action of reagents,
products belonging either to the aromatic, the furfural, or the fatty
group.
_Adipo-cellulose._—Cork or Cuticular Tissue.—From the mode of formation
of cork and cuticular tissues, it has been concluded that they are also
modified celluloses. The aggregate ultimate composition of cork is
represented by the following percentage numbers:
C 65·7
H 8·3
O 24·5
N 1·5
Cork, however, unlike the jute fibre, is by no means chemically simple,
but can be resolved by the action of mere solvents into a number of
proximate constituents, such as acids, a variety of fatty bodies,
nitrogeneous bodies, &c.
Cuticular tissues, such as constitute the covering of fruits, are more
simple in composition; the cuticle of the apple after purification, has
the following percentage composition:
C 73·66
H 11·37
O 14·97
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