A Text-book of Paper-makingCross, C. F. (Charles Frederick)
Science
A Text-book of Paper-making
Cross, C. F. (Charles Frederick)
Paper industry; Papermaking
The cuticular substance of cotton, straw, esparto, &c., are doubtless
similar bodies. These numbers point to a {27} remarkable similarity
in composition to the fats, and, indeed, from the results of his
study of this tissue, Frémy concluded that it was a fat in everything
but its physical properties, of which we may mention insolubility in
alcohol and in ether, and infusibility. This tissue, however, as also
cork, contains a cellulose residue, which may be isolated by any of
the methods of treatment given for ligno-cellulose. Under the action
of boiling nitric acid these tissues are resolved into cellulose
on the one hand, and a series of fatty acids or products of their
decomposition, suberic and adipic acids, &c., on the other; the latter
amounting in the case of cork to 40 per cent. of the weight of the
substance treated. The cellulose obtained by this treatment is but 2–3
per cent.; this number, however, represents only the amount which has
survived a treatment which we know to be destructive to cellulose. If,
on the other hand, cork be resolved by treatment with sodium sulphite
solution at 100lb. pressure, or 166° C. (331° F.), a soft mass is
obtained, preserving the structural features of the original cork,
until subjected to slight pressure, when it falls to a cellular mass.
From this, cellulose is isolated by any of the less drastic processes
above described, and is found to amount to 9–10% of the original cork.
As in ligno-cellulose, we have evidence of a transition from cellulose
to the tannins, so in cork and cuticular tissue we have evidence of
the metamorphosis of cellulose into fats, a fact indicated in the term
_adipo-cellulose_, which we have applied to the compound celluloses
constituting these protective plant tissues. This metamorphosis is
doubtless a very complex process, and would appear to involve the
formation of tannins also, at least as a subsidiary result. Still,
the essential feature of the change is the production of the peculiar
fat-like substances which have been described; and with due regard
to the limitation pointed out, the views here advanced represent the
results of the investigations of the subject as far as they have
proceeded.
It may be observed that the general characteristics of the {28}
adipo-celluloses as of the ligno-celluloses are those of a complex
aldehyde.
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