A Text-book of Paper-makingCross, C. F. (Charles Frederick)
Science
A Text-book of Paper-making
Cross, C. F. (Charles Frederick)
Paper industry; Papermaking
The next processes in the order of the development of our subject,
but not chronologically, are those involving the use of reducing
acids, i.e. those which combine with their hydrolytic function a
de-oxidising or anti-oxidising action. Of these the only one which
has been practically investigated is sulphurous acid. A full account
of the earlier discoveries in regard to the use of this reagent, for
the special purpose under consideration, will be found in the _Papier
Zeitung_, 1884, No. 51, p. 1927; this should be consulted by those who
are interested in the history of a subject which has now grown to be of
the first importance.
The first patented process claiming the use of sulphurous acid, in the
form of its aqueous solution, for the purpose of disintegrating wood,
was that of Tilghmann (1866). So far as is known, however, the results
obtained by the inventor with the acid alone were such as to lead him
to abandon it for solutions containing a certain proportion of base.
The reasons, doubtless, were the greater facility of preparation and
simplicity of application of such solutions.
More recently Professor Pictet, of Geneva, on the basis of the
experience acquired by him in the preparation and employment of
sulphurous acid in his patent freezing processes, has revived and
perfected a process which in other hands had proved impracticable.
The method and apparatus employed will be found fully described in the
author’s specification. The process consists in digesting the wood in
closed vessels with an aqueous solution of the acid (10–12 per cent.
SO_{2}) at 176°–194° F. (80°–90° C.), and under the corresponding
pressure (60–75 lb. per square inch). A complete disintegration of
pine wood is effected in about twenty-four hours’ treatment. The
yield of pulp is, we are informed, from 40–50 per cent. of the wood
(_Pinus sylvestris_); it is also stated to be readily bleached {71}
with a moderate amount of bleaching powder, and to yield a pulp of
the highest quality. Further, the recovery of the sulphurous acid, for
which special apparatus is provided, is practically complete (95–98 per
cent.). In view of the probable utilisation of the bye-products, it is
interesting to observe that they are obtained in a form in which they
can very readily be treated.
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