A Text-book of Paper-makingCross, C. F. (Charles Frederick)
Science
A Text-book of Paper-making
Cross, C. F. (Charles Frederick)
Paper industry; Papermaking
The process being as yet undeveloped on a large scale, we cannot do
more than recommend it to the consideration of paper-makers. At the
same time we would draw attention to the features of interest which
it possesses in regard to the general aspect of our subject. The
resolution which it effects is obviously one of simple hydrolysis, and
it affords an indirect proof of the chemical complications which attend
all other processes for disintegrating wood which employ temperature
much above the boiling-point of water. The soluble bye-products are
obtained in the simplest form, and may be isolated by mere evaporation.
As regards the chemical features of the pulp, they will presumably be
different from those of any other, whether on the side of advantage or
not it remains to decide. Provided the process fulfils the condition
of economical working, we have no hesitation in predicting for it a
considerable development.
The difficulties attending the employment of a gaseous acid have
doubtless operated in deterring many, in addition to the originator,
from a complete investigation of its action, and have led them to adopt
in preference one of its several compounds with bases, the employment
of which defines a group of processes to which we now desire to call
attention. There is a variety of processes agreeing in the essential
feature of employing a bisulphite as the disintegrating reagent, and
differing from one another only in the less essential details of method.
The general principle of these processes will be readily understood
from what has gone before. The chief agency is the hydrolytic action
of sulphurous acid, aided by the conditions of high temperature and
pressure: and the subsidiary {72} agencies are—(1) The prevention of
oxidation; (2) The removal from the sphere of action of the soluble
products of resolution in combination with the sulphite as a true
double compound. This mode of union is well known to be peculiarly
characteristic of all aldehydes, to which class we have shown that the
non-cellulose constituents of wood belong. The combination is expressed
by the general equation—
M.CHO + SO_{3}HNa = M.CH(OH/SO_{3})Na.
Aldehyde. Sodium Double compound.
bi-sulphite.
(3) The removal of a portion of the constituents in combination with
the base, i.e. with expulsion of sulphurous acid.
The verification of these views has been afforded in the course of an
investigation of the bye-products from the Ekman process, undertaken by
the authors for Messrs. Thomson, Bonar & Co., the proprietors of the
patent.
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