A Text-book of Paper-makingCross, C. F. (Charles Frederick)
Science
A Text-book of Paper-making
Cross, C. F. (Charles Frederick)
Paper industry; Papermaking
As the various bisulphite processes differ chiefly in their working
details, the essential feature of the employment of a solution of
sulphurous acid, combined with a certain amount of base, being common
to them all, it will not be necessary to do more than examine one or
two typical cases. We shall select those of Ekman and Partington, the
latter being based upon Francke’s patent, with certain modifications
and additions.
(1) The Chemicals employed.—In both cases sulphur is used as the source
of the sulphurous acid. The Ekman process starts from magnesite, a
native carbonate of magnesia. This is converted by calcination into
magnesia, and in this state is introduced into lead-lined towers,
through which is passed sulphurous acid gas, obtained by burning
sulphur in suitable furnaces, while a stream of water trickles down
from the top. The supply of the gas being properly adjusted, a
continuous production of a solution of magnesium bisulphite of uniform
strength is obtained. To secure this uniformity, constant attention
is necessary, and further, the loss of sulphurous acid by oxidation
to sulphuric acid, and by diffusion, is, in consequence of its
distribution over so large a surface, {73} and with free exposure to
the air, necessarily very large. It is unnecessary, however, to point
out that the preparation of the magnesium bisulphite is capable of
very considerable modification; in fact, we understand that numerous
improvements in this direction have already been introduced by the
proprietors of the process.
Partington’s method, in addition to the advantage of starting
from lime, the cheapest of all basic substances, is free from the
disadvantages referred to as attending the use of a tower. It consists
in passing the sulphurous acid gas through a series of three vessels
connected together with pipes. Into these vessels a charge of milk of
lime is introduced, and the two first being closed air-tight, the gas
is passed in. The third remains open to the air, and from it escapes
a continuous stream of nitrogen, resulting from the removal of the
oxygen by the burning sulphur, from the stream of air which is blown
through the sulphur retort at a pressure of 5 lb. to the square inch.
The expenditure for chemicals is under 1_l._ per ton, whereas, by the
Ekman process, it has been variously estimated at from 2_l._ to 3_l._
10_s._ per ton. Provided therefore, that as good pulp can be obtained
by Partington as by Ekman, the former offers considerable advantages
both from point of view of simplicity and economy. Doubtless the cost
of chemicals could be somewhat reduced in both systems by the adoption
of a cheaper form of sulphur, such as pyrites.
Public-domain text, read in full here on John Shaqi.
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