A Text-book of Paper-makingCross, C. F. (Charles Frederick)
Science
A Text-book of Paper-making
Cross, C. F. (Charles Frederick)
Paper industry; Papermaking
The cellulosic products of the various processes present certain slight
differences, but so far as has been investigated, not such as to
constitute a distinct advantage for one or {75} another. One feature
of these processes, to which but little attention has hitherto been
paid, is that of the utilisation of their bye-products. These bodies
are, as already indicated, obtained in a condition not materially
different from that of the parent substance, the non-cellulose
constituents of the wood. One important property of these bodies, and
one capable of considerable application, has been made the basis of
a patent by the authors. When a solution of gelatin is added to the
liquors in which wood has been treated by any of the bisulphite or
sulphurous acid processes, a body is precipitated in the form of a
caoutchouc-like mass which can be dissolved in neutral sodium sulphite
solution, or in weakly alkaline solutions, and can be reprecipitated on
addition of alum to the solution. The substance consists of a compound
of the gelatin with the non-cellulose constituents resembling, but
not identical with, as has been supposed, the precipitate obtained
by adding tannic acid to a solution of gelatin. The solution of this
substance in sodium sulphite can be applied to many of the purposes to
which gelatin itself is ordinarily applied.
A serious objection to all processes involving the use of sulphurous
acid or acid sulphite, and one which has to some extent deterred
paper-makers from adopting them, is the necessity of using a boiler
lined with lead. In addition to the fact that such boilers are heavy
and costly, they are objectionable on account of the difficulty and
expense of keeping them in thorough repair. This difficulty arises from
the fact that, owing to the different co-efficients of expansion of
lead and iron, the lead lining originally placed in contact with the
iron or steel shell of the boiler, becoming detached on heating, swells
out in various places, which are thus rendered weaker and liable to
fracture. This is especially the case if, in the course of lining the
boiler, any air has been allowed to remain between the two linings.
Various expedients have been proposed to obviate these defects but with
only partial success. Graham (Eng. Pat. No. 5367, 1883) coats the plate
of his boiler by pouring molten lead upon the perfectly clean surface
which has been {76} previously prepared with zinc chloride. Sometimes
minute holes are drilled in the iron plate to allow the escape of air.
Public-domain text, read in full here on John Shaqi.
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