A Text-book of Paper-makingCross, C. F. (Charles Frederick)
Science
A Text-book of Paper-making
Cross, C. F. (Charles Frederick)
Paper industry; Papermaking
Notwithstanding all the attempts that have been made, the use of a
lead-lined boiler is a serious objection, and any process which will
fulfil the conditions on which the bi-sulphite processes depend, and
which at the same time admits of the use of the ordinary iron boilers,
is an obvious desideratum. Such a process is that patented by one of
the authors (Cross, No. 4984, 1880), claiming the use of solutions
of the neutral sulphites with or without the further addition of an
alkali. This process is very suitable for the treatment of fibres such
as straw, jute, &c., but not economically applicable to the preparation
of wood pulp on account of the cost of chemicals. The preservative
effect of the sulphite is shown by the largely increased yield of pulp.
The chief advantages of the various bi-sulphite processes for the
preparation of wood pulp over the old soda processes are, (1) the
increased yield of fibre; (2) the preservation of its original
strength, and (3), the economy in chemicals.
It is well known that cellulose, even in its most stable forms, is
attacked more or less by hot solutions of the caustic alkalis, and
is more or less profoundly modified according to the strength of the
solution and the temperature at which it is employed; while on the
other hand the solutions of the bisulphites affect it but little. Thus,
the authors have exposed jute cellulose, which is of the same nature
as that obtained from wood, to the action of magnesium bisulphite
under the conditions which obtain in the Ekman process, without its
undergoing sensible loss of weight, and further, they have determined
the amount of cellulose in freshly cut grasses, in which it is but
imperfectly elaborated, and therefore very susceptible of modification,
both before and after treatment by the process, and in each case the
percentage obtained was the same.
There is therefore no doubt that in the bisulphite processes, even
the structurally delicate forms of cellulose are conserved. As before
indicated, the influence of this upon the yield of cellulose is of
course very marked; the yield from white pine, {77} by the soda
process, being approximately 33 per cent., whereas by the Ekman process
it is from 45–50 per cent. It is important to remember that this
increased yield of cellulose cannot fail to affect the quality, and
therefore the paper-making properties of the pulp. Papers made entirely
by the bisulphite processes have a strongly marked individuality, being
distinguished by their hardness and transparency. In regard to the
bleaching of the pulp, it will be found that some practical experience
is required for the control of the operation, so as to produce uniform
results.
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