A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.Procter, H. R. (Henry Richardson)
Science
A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.
Procter, H. R. (Henry Richardson)
Tanning
was not precipitated by iron or mercuric chloride, copper sulphate, nor
by neutral lead acetate; but was precipitated by basic lead acetate,
basic iron sulphate, and excess of tannin. Its elementary composition
is--carbon, 45·91: hydrogen, 6·57; nitrogen, 17·82; oxygen, 29·60; and
Reimer proposes the following equation as representing its relation to
hide fibre:--
Hide fibre. Water. Coriin.
C_{30}H_{46}N_{10}O_{12} + O + 2H_{2}O = C_{30}H_{50}N_{10}O_{15}.
[Footnote C: Dingler's Polyt. Journal, vol. 220, p. 167.]
_Hide Albumen._--The fresh hide, besides this coriin (which, very
possibly, is only evolved by the action of the lime), contains a
portion of actual albumen, viz. that of the blood serum and of the
lymph, which is not only contained in the abundant blood-vessels,
but saturates the fibrous connective tissue, of which it forms
the nourishment. This albumen is mostly removed by the liming and
working on the beam, which is preparatory to tanning. Probably for
sole-leather, the albumen itself would be rather advantageous if left
in the hide, as it combines with tannin, and would assist in giving
firmness and weight to the leather. It is, however, for reasons which
will be seen hereafter, absolutely necessary to get rid of any lime
which may be in combination with it. The blood also must be thoroughly
cleansed from the hide before tanning, as its colouring matter contains
iron, and, in combination with the tannin, would give a bad colour.
The reactions of blood and lymph albumen are very similar to those
of ordinary white of egg. It is precipitated by strong mineral acids,
especially nitric, and also by boiling. The precipitate produced by
strong hydrochloric acid redissolves by the aid of heat to a blue
or purple solution. Tribasic phosphoric, tartaric, acetic, and most
other organic acids, do not precipitate moderately dilute solutions
of albumen, but convert it into a sort of jelly, which, like gelatin,
does not coagulate, but liquefies on heating. It is precipitated by
neutral salts of the alkali metals. Blood-albumen slightly acidified
(with acetic acid) is precipitated by potassium ferrocyanide. It is
not precipitated by dilute infusions of oak bark, but is rendered
uncoagulable by heat, hence it cannot be employed to remove tannins
from their solutions.
_Elastic Fibres._--The elastic or yellow fibres of the hide are of
a very stable character. They are not completely dissolved even by
prolonged boiling, and acetic acid and hot solutions of caustic
alkalies scarcely attack them. Probably they do not combine with
tannin, and are very little changed in the tanning process.
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