A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.Procter, H. R. (Henry Richardson)
Science
A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.
Procter, H. R. (Henry Richardson)
Tanning
_Hair, Epidermis, and Glands._--These are, as has been seen, all
derived from the epithelial layer, and hence, as might be inferred,
have much in common in their chemical constitution. They are all
classed by chemists under one name, "keratin," or horny tissue, and
their ultimate analysis shows that in elementary composition they
nearly agree. It is evident, however, that the horny tissues are rather
a class than a single compound.
The keratins are gradually loosened by prolonged soaking in water,
and, by continued boiling in a Papin's digester, are dissolved to an
extract which does not gelatinise on cooling. Keratin is dissolved by
caustic alkalies; the epidermis and the softer horny tissues are easily
attacked, while hair and horn require strong solutions and the aid of
heat to effect complete solution. The caustic alkaline earths act in
the same manner as dilute alkaline solutions; hence lime easily attacks
the epidermis, and loosens the hair, but does not readily destroy the
latter. Alkaline sulphides, on the other hand, seem to attack the
harder tissues with at least the same facility as the soft ones, the
hair being often completely disintegrated, while the epidermis is still
almost intact; hence their applicability to unhairing by destruction of
the hair. Keratins are dissolved by fuming hydrochloric acid, with the
production of a blue or violet coloration, like the albuminoids. They
also resemble albumen, in the fact that their solution in sulphuric
acid is precipitated by potassium ferrocyanide. By fusion with potash,
or prolonged boiling with dilute sulphuric acid, keratin is decomposed,
yielding leucin, tyrosin, ammonia, &c. The alkaline solution of keratin
(hair, horns, &c.) is precipitated by acids, and, mixed with oil and
baryta sulphate, is employed under Dr. Putz's patent as a filling
material for leather, for which purpose it acts in the same way as the
egg-yolks and meal used in kid-leather manufacture. Eitner attempted
to use it for the same purpose with bark-tanned leather, but without
much success. Putz has also proposed to precipitate the material after
working its solution into the pores of the leather.
CHAPTER III.
COMMERCIAL TANNING MATERIALS.
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