Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
AMOUNTS OF IMPURITIES AND SCOPE OF PURIFICATION.--Partly for the reason
which has just been given, and partly on the ground of expense, a
complete removal of the impurities from crude acetylene is not desirable.
All that need be done is to extract sufficient to deprive the gas of its
injurious effects upon lungs, decorations, and burners. As it stands,
however, such a statement is not sufficiently precise to be useful either
to consumers of acetylene or to manufacturers of plant, and some more or
less arbitrary standard must be set up in order to define the composition
of "commercially pure" acetylene, as well as to gauge the efficiency of
any process of purification. In all probability such limit may be
reasonably taken at 0.1 milligramme of either sulphur or phosphorus
(calculated as elementary bodies) per 1 litre of acetylene, _i.e._,
0.0-1.1 grain per cubic foot; a quantity which happens to correspond
almost exactly with a percentage by weight of 0.01. Owing to the atomic
weights of these substances, and the very small quantities being
considered, the same limit hardly differs from that of 0.01 per cent. by
weight of sulphuretted hydrogen or of phosphine--it being always
recollected that the sulphur and phosphorus do not necessarily exist in
the gas as simple hydrides. Keppeler, however, has suggested the higher
figure of 0.15 milligramme of either sulphur or phosphorus per litre of
acetylene (=0.066 grain per cubic foot) for the maximum amount of these
impurities permissible in purified acetylene. He adopts this standard on
the basis of the results of observations of the amounts of sulphur and
phosphorus present in the gas issuing from a purifier charged with
heratol at the moment when the last layer of the heratol is beginning to
change colour. No limit has been given for the removal of the ammonia,
partly because that impurity can more easily, and without concomitant
disadvantage, be extracted entirely; and partly because it is usually
removed in the washer and not in the true chemical purifier.
Public-domain text, read in full here on John Shaqi.
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